The oxidation of 1,1-dimethylhydrazine by bromine has been studied using a coulometric method of bromine generation, and a dual intermediate system of bromide and cupric ions in solution. The system allowed over-generation of bromine and back-titration by cupric ion. The results of the investigation showed that the mechanism of oxidation is not fixed, but is a function of the concentration of bromine in the solution at any time. Additional studies have been recommended, whereby the mechanisms of the reactions may be determined.
| Identifer | oai:union.ndltd.org:BGMYU2/oai:scholarsarchive.byu.edu:etd-9193 |
| Date | 01 May 1962 |
| Creators | Creighton, David M. |
| Publisher | BYU ScholarsArchive |
| Source Sets | Brigham Young University |
| Detected Language | English |
| Type | text |
| Format | application/pdf |
| Source | Theses and Dissertations |
| Rights | http://lib.byu.edu/about/copyright/ |
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