A variable temperature 1H, 13C, and 6Li NMR study of n-propyl-6Li-lithium showed five different aggregates, similar to that in the literature as (RLi)n, n= 6, 8, 9, 9, 9. There were also a number of additional new species, identified as lithium hydride containing aggregates. Unexpectedly, a series of 13C{1H} 1-D NMR experiments with selective 6Li decoupling showed evidence for 13C-6Li spin-spin coupling between the previously reported (RLi)n aggregates and various hydride species.
Identifer | oai:union.ndltd.org:unt.edu/info:ark/67531/metadc3350 |
Date | 12 1900 |
Creators | Davis, James W. |
Contributors | Thomas, Ruthanne D., Richmond, Michael |
Publisher | University of North Texas |
Source Sets | University of North Texas |
Language | English |
Detected Language | English |
Type | Thesis or Dissertation |
Format | Text |
Rights | Public, Copyright, Davis, James W., Copyright is held by the author, unless otherwise noted. All rights reserved. |
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