<p> The hydrogenolysis reactions of a series of small paraffinic hydrocarbons (propane, n-butane, isobutane, isopentane, and neopentane) were examined using a continuous stirred-tank catalytic reactor. The catalyst was 0.5 weight percent ruthenium scipported on γ-alumina.</p> <p> The reaction orders with respect to hydrocarbon and hydrogen and the activation energies were determined for the reaction of each hydrocarbon. The order of reactivity was also examined.</p> <p> The product distributions from each hydrocarbon were measured over a wide range of conversion (5 to 80%) and several temperatures. Reaction networks proposing reversible adsorption-desorption of the hydrocarbons and irreversible rupture of the carbon-carbon bonds in the surface species were applied to these data.</p> <p> Some conclusions were made concerning the mechanism of hydrogenolysis and the rate-limiting step.</p> / Thesis / Doctor of Philosophy (PhD)
| Identifer | oai:union.ndltd.org:mcmaster.ca/oai:macsphere.mcmaster.ca:11375/18572 |
| Date | 01 1900 |
| Creators | Kempling, John Christopher |
| Contributors | Anderson, R. B., Chemical Engineering |
| Source Sets | McMaster University |
| Language | en_US |
| Detected Language | English |
| Type | Thesis |
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