<p> The cryoscopic constant for fluorosulphuric acid has been determined and the nature and concentration of the impurities in the solvent have been investigated.</p> <p> The NMR and Gouy methods have been used to determine the magnetic susceptibility of solutions of iodine fluorosulphates. The NMR method has been shown to lead to spurious results.</p> <p> Cryoscopy, conductivity and UV and visual spectrophotometry have been used to elucidate the state of iodine fluorosulphates in fluorosulphuric acid. Solutions of stoichiometry corresponding to fifth-, third-, half-, uni-, tri-, and hepta-valent iodine have been investigated. The highest valence state observed was that of iodine trifluorosulphate which
has been shown to be an acid in fluorosulphuric acid. Measurements on fifth- and third-valent iodine solutions indicate that I5+ and I3+ are formed. Measurements on half- and univalent iodine solutions suggest that I2+ is formed. The observed magnetic moment of this species agrees well with that required by theory, 2.0 BM.</p> / Thesis / Doctor of Philosophy (PhD)
| Identifer | oai:union.ndltd.org:mcmaster.ca/oai:macsphere.mcmaster.ca:11375/19695 |
| Date | 08 1900 |
| Creators | Milne, John Buchanan |
| Contributors | Gillespie, R. J., Chemistry |
| Source Sets | McMaster University |
| Language | en_US |
| Detected Language | English |
| Type | Thesis |
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