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Previous issue date: 2015-03-31 / Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior - CAPES / In this work, it was evaluated the possibility of using bark of black wattle (Acacia mearnsii) as a corrosion inhibitor in environments with presence of CO2 under high pressure. SAE 1010 carbon steel samples were exposed to two corrosive situations (with and without oxygen) under the conditions of 15 MPa and 70 ?C, with distinct tannin concentrations for different exposure times (168, 360 and 2160 hours). In order to characterize the specimens it was used infrared spectroscopy analysis, Xray diffraction, scanning electron microscopy by field emission, energy dispersive spectroscopy, mass loss and potentiodynamic polarization tests, determining the rate of corrosion and the efficiency tannin as of tannin as inhibitor. The results indicated that the tannin in deaerated environmental has no potential for use as an inhibitor once there was no significant reduction in corrosion rates and, also the formation of ferric-tannates film. Was not observed corrosion rates values, due mass loss, and were classified as severe corrosion, according to values of NACE RP-07-75 and was not inhibition efficiency values higher than 21 % obtained. Nevertheless, in aerated environmental, tannin worked as a barrier to diffusion of O2 and/or complexation of Fe2+ and Fe3+, providing favorable conditions to the formation of FeCO3 film with protective features. The corrosion rates were classified as moderate for 2160 hours, while 168 h and 360 h, as severe, also according to the values of NACE-RP-07-75, reaching values of up to 72% inhibition efficiency. / Neste trabalho, avaliou-se a possibilidade de utiliza??o do tanino vegetal da ac?cia negra (Acacia mearnsii) como inibidor de corros?o em ambientes com a presen?a de CO2 a alta press?o. Corpos de prova de a?o SAE 1010 foram expostos a dois meios corrosivos (sem e com O2) sob condi??es de 15 MPa e 70?C, com diferentes concentra??es de tanino para diferentes tempos de exposi??o (168, 360 e 2160 h). Para caracteriza??o foram realizadas an?lises de espectroscopia de infravermelho, difra??o de raios X, microscopia eletr?nica de varredura por emiss?o de campo, espectroscopia de energia dispersiva, perda de massa e ensaios de polariza??o potenciodin?mica, determinando-se a taxa de corros?o e a efici?ncia do tanino como inibidor. Os resultados indicaram que o tanino, em meio desaerado, n?o apresenta potencial para utiliza??o como inibidor, pois n?o houve redu??o significativa nas taxas de corros?o e tamb?m n?o se observou a forma??o do filme de ferrotanatos. Todos os valores de taxas de corros?o, por perda de massa, foram classificados como corros?o severa, segundo valores da NACE-RP-07-75 e n?o se obteve valores de efici?ncia de inibi??o maiores que 21 %. No entanto, em meio aerado, o tanino atuou como barreira para a difus?o de O2 e/ou na complexa??o dos ?xidos de Fe2+ e Fe3+, formando filmes de ferrotanatos, propiciando condi??es favor?veis para a forma??o do filme de FeCO3 com caracter?sticas protetoras. As taxas de corros?o foram classificadas como moderada para 2160 h, enquanto que para 168 h e 360 h, como severa, tamb?m segundo valores da NACE-RP-07-75, atingindo-se valores de at? 72 % de efici?ncia de inibi??o.
| Identifer | oai:union.ndltd.org:IBICT/oai:tede2.pucrs.br:tede/6273 |
| Date | 31 March 2015 |
| Creators | Marcolino, Juliane Bernardes |
| Contributors | Costa, Eleani Maria da |
| Publisher | Pontif?cia Universidade Cat?lica do Rio Grande do Sul, Programa de P?s-Gradua??o em Engenharia e Tecnologia de Materiais, PUCRS, Brasil, Faculdade de Engenharia |
| Source Sets | IBICT Brazilian ETDs |
| Language | Portuguese |
| Detected Language | Portuguese |
| Type | info:eu-repo/semantics/publishedVersion, info:eu-repo/semantics/doctoralThesis |
| Format | application/pdf |
| Source | reponame:Biblioteca Digital de Teses e Dissertações da PUC_RS, instname:Pontifícia Universidade Católica do Rio Grande do Sul, instacron:PUC_RS |
| Rights | info:eu-repo/semantics/openAccess |
| Relation | -7432719344215120122, 600, 600, 600, 600, -655770572761439785, 4518971056484826825, 2075167498588264571 |
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