Wang, Yang. / "October 2011." / Thesis (M.Phil.)--Chinese University of Hong Kong, 2012. / Includes bibliographical references (leaves 87-92). / Abstracts in English and Chinese. / Acknowledgement --- p.I / Abstract (in English) --- p.III / Abstract (in Chinese) --- p.IV / Abbreviation --- p.V / List of Compounds --- p.VI / List of Figures --- p.IX / Contents --- p.X / Chapter Chapter 1 --- Introduction --- p.1 / Chapter 1.1 --- Synthesis and Structure of Half-Sandwich Group 4 Metallocarboranes Containing the Dicarbollyl Ligand --- p.2 / Chapter 1.2 --- Half-Sandwich Group 4 Metallacarboranes Catalyzed Reactions --- p.20 / Chapter 1.2.1 --- Polymerization of Olefins --- p.20 / Chapter 1.2.2 --- Catalytic Dimerization and Hydrogenation of Alkynes --- p.22 / Chapter 1.2.3 --- Catalytic Addition of Amines to Carbodiimides --- p.23 / Chapter 1.2.4 --- Catalytic Transamination of Guanidines --- p.24 / Chapter 1.2.5 --- Catalytic Synthesis of A^-Heterocycles --- p.25 / Chapter 1.3 --- Research Objectives of This Thesis --- p.26 / Chapter Chapter 2 --- Half-Sandwich Group 4 Metallacarborane Monoamindes --- p.27 / Chapter 2.1 --- Introduction --- p.27 / Chapter 2.2 --- Synthesis of Dicarbollyl Ligands Bearing Functional Side Arms --- p.27 / Chapter 2.3 --- Synthesis and Characterization of Half-Sandwich Group 4 Metallacarborane Monoamindes --- p.33 / Chapter 2.4 --- Summary --- p.43 / Chapter Chapter 3 --- Synthesis of 2-Aminoimidazoles Catalyzed by Half-Sandwich Titanacarborane Monoamide --- p.44 / Chapter 3.1 --- Introduction --- p.45 / Chapter 3.2 --- Known Methods for the Synthesis of 2-Aminoimidazole --- p.44 / Chapter 3.2.1 --- Condensations Methods --- p.44 / Chapter 3.2.2 --- Direct Introduction of N at C2 Position --- p.46 / Chapter 3.2.3 --- Heterocyclic Exchange Reactions --- p.47 / Chapter 3.2.4 --- Transition Metal Catalyzed Reactions --- p.48 / Chapter 3.3 --- Results and Discussion --- p.49 / Chapter 3.3.1 --- Synthesis of Propargy 1 Amines --- p.49 / Chapter 3.3.2 --- Synthesis and Characterization of 2-Aminoimidazoles --- p.50 / Chapter 3.3.3 --- Proposed Reaction Mechanism --- p.55 / Chapter 3.4 --- Summary --- p.57 / Chapter Chapter 4 --- Conclusion --- p.59 / Chapter Chapter 5 --- Experimental Section --- p.61 / References --- p.87 / Appendix / Chapter I. --- Publication Based on the Research Findings --- p.93 / Chapter II. --- Crystal Data and Summary of Data Collection and Refinement --- p.94 / Chapter III. --- X-ray crystallographic data in CIF (electronic form)
| Identifer | oai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_327627 |
| Date | January 2012 |
| Contributors | Wang, Yang., Chinese University of Hong Kong Graduate School. Division of Chemistry. |
| Source Sets | The Chinese University of Hong Kong |
| Language | English, Chinese |
| Detected Language | English |
| Type | Text, bibliography |
| Format | print, xi, 94 leaves : ill. ; 30 cm. |
| Rights | Use of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/) |
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