In the present work, the results of the experimental study of reactions of ions with molecular hydrogen in the temperature range 15 - 300 K using a 22-pole ion trap apparatus are presented. The reaction of OD- with para-enriched hydrogen was studied using a combination of the 22-pole ion trap apparatus with a para-hydrogen generator. Also reactions of O- with H2, D2, and HD were studied. These reactions have a channel of water production and a channel of hydrogen or deuterium transfer. Another field of study was a sequence of reactions of oxygen hydride cations with H2 and D2 which leads to the production of H3O+ or its isotopic variant, specifically reactions OH+ with H2, H2O+ with H2, D2O+ with H2, and D2O+ with D2. This reaction chain can be followed by the electron recombination of H3O+ or its isotopologue, which has a channel of water production.
| Identifer | oai:union.ndltd.org:nusl.cz/oai:invenio.nusl.cz:411460 |
| Date | January 2020 |
| Creators | Tran, Thuy Dung |
| Contributors | Plašil, Radek, Španěl, Patrik, Rubovič, Peter |
| Source Sets | Czech ETDs |
| Language | English |
| Detected Language | English |
| Type | info:eu-repo/semantics/doctoralThesis |
| Rights | info:eu-repo/semantics/restrictedAccess |
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