Electrochemical frequency modulation (EFM), which has been widely used in the research field of semiconductors, was used to study CO2 corrosion on carbon steel under film forming and non-film forming conditions. In the EFM technique two sinusoidal voltage signals of different frequencies are applied to the system and the response current is measured at zero, harmonic and intermodulation frequencies from which the corrosion rate is calculated. The corrosion rate calculation depends upon whether the system is under activation, diffusion or passivation control. In this research rotating cylindrical electrodes made of AISI carbon steel 1018 were immersed in 3% (w/w) NaCl solution saturated with carbon dioxide. The experiment was done at 5 rpm, 24 rpm and 100 rpm simulating laminar, transient and turbulent flow regions respectively. The exposure time was varied from 1 hour to 24 hours and the results were compared with other electrochemical methods such as linear polarization (LP) and electrochemical impedance spectroscopy (EIS). It was found that it was crucial to select the correct EFM model to ensure accurate corrosion rate measurement. A very good agreement in the polarization resistance was obtained between EIS and EFM indicating that EFM can be used as an effective tool in corrosion studies providing that the corrosion mechanism is known.
| Identifer | oai:union.ndltd.org:LACETR/oai:collectionscanada.gc.ca:SSU.etd-07012009-110957 |
| Date | 15 July 2009 |
| Creators | Sridharan, Venkatasubramaniyan |
| Contributors | Phoenix, Aaron, Oguocha, Ikechukwuka N., Hill, Gordon A., Evitts, Richard W., Scott, Robert |
| Publisher | University of Saskatchewan |
| Source Sets | Library and Archives Canada ETDs Repository / Centre d'archives des thèses électroniques de Bibliothèque et Archives Canada |
| Language | English |
| Detected Language | English |
| Type | text |
| Format | application/pdf |
| Source | http://library.usask.ca/theses/available/etd-07012009-110957/ |
| Rights | unrestricted, I hereby certify that, if appropriate, I have obtained and attached hereto a written permission statement from the owner(s) of each third party copyrighted matter to be included in my thesis, dissertation, or project report, allowing distribution as specified below. I certify that the version I submitted is the same as that approved by my advisory committee. I hereby grant to University of Saskatchewan or its agents the non-exclusive license to archive and make accessible, under the conditions specified below, my thesis, dissertation, or project report in whole or in part in all forms of media, now or hereafter known. I retain all other ownership rights to the copyright of the thesis, dissertation or project report. I also retain the right to use in future works (such as articles or books) all or part of this thesis, dissertation, or project report. |
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