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The Substituent effect of B-diketonato Metal Complexes containing DMF

In this study, we focus on the substituent effect of the diketone ligands on the structural variation of £]- diketonato metal complexes containing N,N-dimethyl formamide (DMF). Three £]-diketones (hfac, bztf, bzbz) were used, and six-, five-, four- coordinated complexes were found accordingly. It is surprising to find that all six metal-oxygen bonds in the M(hfac)2(DMF)2 complexes are of equal length, seemly in violation of Jahn-Teller theorem. Possible reasons for this observation were discussed in this thesis.

Identiferoai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0827101-155903
Date27 August 2001
CreatorsYung, Tun-Yuang
Contributorsnone, none, Michael Yen-nan Chiang
PublisherNSYSU
Source SetsNSYSU Electronic Thesis and Dissertation Archive
LanguageCholon
Detected LanguageEnglish
Typetext
Formatapplication/pdf
Sourcehttp://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0827101-155903
Rightswithheld, Copyright information available at source archive

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