The ayelodehydrogenation of 7-(1-naphthyl)benz [a] anthracene to dibenzo [a,e] perylene was accomplished in 38% yield using an aluminum chloride - stannic chloride catalyst. Attempts to reproduce or to improve this yield were not successful and thereafter the only product isolated was a low melting light orange solid which was postulated to be a hydrogenated intermediate. That the orange material could be converted to dibenzo [a,e] perylene upon treatment with palladiem on charcoal in p-eymene substantiated this postulation. / Master of Science
| Identifer | oai:union.ndltd.org:VTETD/oai:vtechworks.lib.vt.edu:10919/43027 |
| Date | 10 June 2012 |
| Creators | Pavlik, James William |
| Contributors | Chemistry, Vingiello, Frank A. |
| Publisher | Virginia Tech |
| Source Sets | Virginia Tech Theses and Dissertation |
| Language | English |
| Detected Language | English |
| Type | Thesis, Text |
| Format | 59 leaves, BTD, application/pdf, application/pdf |
| Rights | In Copyright, http://rightsstatements.org/vocab/InC/1.0/ |
| Relation | OCLC# 22537077, LD5655.V855_1961.P384.pdf |
Page generated in 0.0064 seconds