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Synthesis of some compounds of possible carcinogenic activity

1. The acid catalyzed cyclodehydration method was extended to the 9-aryl-1,2-benzanthracene and 9-naphthylanthracene series.

2. A new method of cyeclodehydration was described.

3. The series of 10-mono- and 10-dimethylphenyl-1,2-benzanthracenes was completed. All the isomeric 9-mono- and 9-dimethylphenyl-1,2-benzanthracenes were prepared together with the corresponding ketones. Some highly hindered ketones were prepared and their cyclization realized. A total of 47 compounds, not previously reported in the literature, were synthesized.

4. The spectra of 24 hydrocarbons were recorded and the theory of nonplanarity of these compounds substantiated. / Ph. D.

Identiferoai:union.ndltd.org:VTETD/oai:vtechworks.lib.vt.edu:10919/37187
Date12 January 2010
CreatorsBorkovec, Alexej B.
ContributorsChemistry, Vingiello, Frank A., Murray, John W., King, Kendall W.
PublisherVirginia Tech
Source SetsVirginia Tech Theses and Dissertation
LanguageEnglish
Detected LanguageEnglish
TypeDissertation, Text
Format145 leaves, BTD, application/pdf, application/pdf
RightsIn Copyright, http://rightsstatements.org/vocab/InC/1.0/
RelationOCLC# 20499636, LD5655.V856_1955.B674.pdf

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