For the entire alkali feldspar series, Σt₁ (total Al content in the T₁ sites, a quantitative measure of structural state or Al,Si long-range ordering) can be closely estimated from X<sub>Or</sub> (mole fraction of KAlSi₃O₈) and Y<sub>x</sub> (one half of the optic axial angle 2V<sub>x</sub>) by use of a simple determinative diagram based on the model
Σt₁ = (b₀ + b₁X<sub>Or</sub> + b₂X<sub>Or</sub>sin²V<sub>x</sub> + b₃sin²V<sub>x</sub>) / (a₀ + a₁X<sub>Or</sub> + a₂X<sub>Or</sub>sin²V<sub>x</sub> + a₃sin²V<sub>x</sub>).
Three sets of coefficients for this equation are required to account for three cases: (A) where X<sub>Or</sub> ≤ 0.6; (B) where X<sub>Or</sub> > 0.6 and O.A.P. (optical axial plane) ~ ⊥ (010); and (C) where X<sub>Or</sub> > 0.6 and O.A.P. = (010). They are (multiplied by 1000):
<table style =”width:100%”>
<tr><th>Case</th><th>a₀</th><th>a₁</th><th>a₂</th><th>a₃</th><th>b₀</th><th>b₁</th><th>b₂</th><th>b₃</th></tr>
<tr><td>A</td><td>4.08</td><td>-2.35</td><td>0.95</td><td>-1.28</td><td>1.52</td><td>-0.18</td><td>-1.74</td><td>2.88</td></tr>
<tr><td>B</td><td>1.69</td><td>1.63</td><td>-2.33</td><td>0.69</td><td>0.11</td><td>2.17</td><td>-2.70</td><td>3.46</td></tr>
<tr><td>C</td><td>-1.69</td><td>-1.63</td><td>-0.70</td><td>2.38</td><td>-0.11</td><td>-2.17</td><td>-0.53</td><td>3.57</td></tr>
</table>
Tested by the data from 109 alkali feldspars in the literature and the author's experiments, this model estimates Σt₁ (given X<sub>Or</sub> and V<sub>x</sub>) with a standard error of 0.02, which is essentially the same as when Σt₁ is estimated from refined lattice parameters determined by X-ray diffraction methods.
The model was developed by assuming that the principal refractive indices for sodium light - symbolized as n<sub>a</sub>, n<sub>b</sub>, and n<sub>c</sub> dependent upon whether the corresponding principal vibration axis was parallel or most nearly parallel to crystallographic axes a, b and c - varied linearly with Σt₁ for the high-sanidine to low-microcline series and for the low albite to high albite (or analbite) series. However, for the high albite to high sanidine solid solution series, as well as the low albite to low microcline series, neither density nor principal refractive indices vary linearly across the entire composition range, but they closely approached linearity between 0.0 ≤ X<sub>Or</sub> < 0.6 and 0.6 < X<sub>Or</sub> ≤ 1.0. / Ph. D.
| Identifer | oai:union.ndltd.org:VTETD/oai:vtechworks.lib.vt.edu:10919/71274 |
| Date | January 1986 |
| Creators | Su, Shu-Chun |
| Contributors | Geology, Gibbs, Gerald, Stewart, David B., Wondratschek, Hans, Bloss, F. Donald, Ribbe, Paul H. |
| Publisher | Virginia Polytechnic Institute and State University |
| Source Sets | Virginia Tech Theses and Dissertation |
| Language | en_US |
| Detected Language | English |
| Type | Dissertation, Text |
| Format | xi, 128 leaves, application/pdf, application/pdf |
| Rights | In Copyright, http://rightsstatements.org/vocab/InC/1.0/ |
| Relation | OCLC# 15048204 |
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