The effect of the interphase/interface region on the static mechanical properties, creep and creep rupture behavior of thermoplastic (J2) composites was investigated. The mechanical properties of the J2 composites were altered by systematic changes in fiber surface chemistry. Four fiber systems were used including the AU4, AS4(1) & (2), and AS4CGP fibers. (AS4(1) and AS4(2) represent different batch numbers.) Surface energies and chemistry of carbon fibers were examined using the Dynamic Contact Angle (DCA) method and X-ray Photoelectron Spectroscopy (XPS), respectively. The meso indentation technique was used to measure the interfacial shear strengths (ISS) of the composites.
For the same batch of the composites, the ISS ratios for AS4(2)/J2 to AU4/J2 and AS4CGP/J2 to AU4/J2 were 1.22 and 1.24, respectively. The mechanical properties of these composites in the fiber direction were insensitive to the ISS. The transverse and shear moduli of the J2 composites were also not affected by the ISS. The static strengths, in general, ordered themselves from strong to weak as follows: AS4(2)/J2> AS4CGP/J2> AU4/J2. However, the creep rupture strength revealed a different ordering: AS4CGP/J2> AS4(2)/J2> AU4/J2. This suggests that static mechanical properties may not be a good indicator for long term mechanical performance. Experimental results showed that the interphase/interface region did not affect the degradation rates of the creep rupture strength of the J2 composites.
DMA creep tests were performed at elevated temperatures for J2 composites. A master curve of each composite was generated. The shift factors obeyed the Arrhenius type equation. The activation energies of composites were approximately the same. The creep response of the AU4/J2, AS4(2)/J2, and AS4CGP/J2 composites were not dependent upon the ISS.
Severe delaminations were observed in the AS4(1)/Jd2 composite laminates. The ([±45/90₂]<sub>s</sub>) laminate tensile strength of AS4(1)/J2 composite was less than that of AS4(2)/J2 and AS4CGP/J2 composite. The creep rupture strength of the AS4(1)/J2 composite laminates degraded about two times faster than that of the other three composite systems. / Ph. D.
| Identifer | oai:union.ndltd.org:VTETD/oai:vtechworks.lib.vt.edu:10919/38439 |
| Date | 06 June 2008 |
| Creators | Chang, Yeou Shin |
| Contributors | Materials Engineering Science, Dillard, David A., Baird, Donald G., Loos, Alfred C., Stinchcomb, Wayne W., Ward, Thomas C. |
| Publisher | Virginia Tech |
| Source Sets | Virginia Tech Theses and Dissertation |
| Language | English |
| Detected Language | English |
| Type | Dissertation, Text |
| Format | xi, 154 leaves, BTD, application/pdf, application/pdf |
| Rights | In Copyright, http://rightsstatements.org/vocab/InC/1.0/ |
| Relation | OCLC# 26248042, LD5655.V856_1992.C526.pdf |
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