III-V nitride based light-emitting diodes (LEDs) have experienced rapid developments during past decade, proving their potential to substitute conventional incandescent bulbs and fluorescent lamps to fulfil energy-efficient and sustainable lighting needs. Tremendous endeavours have been made to improve the performance of LEDs, most of which focused on enhancing the internal and external quantum efficiencies. However, other optical properties of LEDs remain to be explored for a more flexible way of using LEDs in various applications. Therefore, this thesis proposes two nanostructuring strategies through the use of nanospheres to tailor the optical properties of LEDs. The nanostructured LEDs are demonstrated enable light emission with reduced divergence, or becomes polarized. The monolithic modifications are free of external optics and thus eliminate light loss, meanwhile providing manipulability of optical emission from LEDs.
Firstly, close-packed indium-tin-oxide (ITO) micron-lenses with dimension of the order of wavelength have been integrated onto InGaN LEDs aiming at reducing the emission divergence. The sub-micron lens arrays are patterned by nanosphere lithography with silica nanosphere serving as an etch mask on ITO layer, leaving the semiconductor layer damage-free. An enhancement of up to 63.5% on optical output power from the lensed LED has been observed. The LED with 500 nm lenses exhibits a 26.8° reduction in emission divergence (full width at half maximum) compared with the bare LED. Three-dimensional finite-difference time-domain simulations performed for light extraction and emission characteristics is found to be consistent with the observed results.
Secondly, polarization behavior of light emitted from InGaN LEDs propagating through a self-assembled polystyrene nanosphere opal film has been studied. Angular-resolved optical transmission of transverse electric (TE) and transverse magnetic (TM) polarized light has been measured. An integrated p/s ratio of 2.16 is observed at a detection angle of 70°, attributed to the suppression of TE mode at particular frequencies by the three-dimensional photonic crystal. Polarization is found to depend strongly on both the photonic bandgap of the opal and the angle of incidence. Theoretical calculations by transfer matrix method yield results consistent with the experimental data. / published_or_final_version / Electrical and Electronic Engineering / Master / Master of Philosophy
| Identifer | oai:union.ndltd.org:HKU/oai:hub.hku.hk:10722/161585 |
| Date | January 2012 |
| Creators | Zhang, Qian, 张倩 |
| Contributors | Choi, HW |
| Publisher | The University of Hong Kong (Pokfulam, Hong Kong) |
| Source Sets | Hong Kong University Theses |
| Language | English |
| Detected Language | English |
| Type | PG_Thesis |
| Source | http://hub.hku.hk/bib/B4807990X |
| Rights | The author retains all proprietary rights, (such as patent rights) and the right to use in future works., Creative Commons: Attribution 3.0 Hong Kong License |
| Relation | HKU Theses Online (HKUTO) |
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