A rotating disk technique was used to determine the dissolution rate and diffusivity of CaO and MgO in slags. The dissolution rate was deduced from the measured changes in concentration of oxides in slag with respect to reaction time. The experimental set- up was initially tested with dissolution of magnesia in the CaO ??? 55 wt% Al2O3 slag at 1430 ??C and a measured rate of 2.7 ??10 -5 g/cm2.s was obtained. The dissolution rate was increased by slag chemistry and ranged from 6.5??10-5 to 2.1??10-4 g/cm2.s. The dissolution rate of CaO was measured in CaO ??? 42 wt% Al2O3 ??? 8% SiO2 based slag. The measured dissolution rates were found to be strongly dependent on the slag chemistry and temperature and ranged from 5.03??10 -5 to 3.3??10 -4 g/cm2.s. The dissolution rates were strongly dependent on the rotation speed and results indicate mass transfer in the slag phase to be rate- limiting step. The diffusivity of MgO / CaO was calculated from the dissolution rate and solubility data, using known mass transfer correlations. The diffusivity of MgO in the calcium aluminate slag at 1430 ??C was found to be about 1.1??10-5 cm2/s. Additions of 5 and 10 wt% Fe2O3 increased the diffusivity by a factor ~ 1.5 to 3, respectively. However, with introduction of (CaF2 5 wt% + Fe2O3 5 wt%) and (CaF2 5 wt% + Fe2O3 10 wt%) in the slag, the diffusivity increased considerably by a factor of about 29 and 11, respectively. The diffusivity of CaO in calcium aluminosilicate was measured to be in the order of 10-6 to 10-5 over a temperature range of 1430 ??? 1600 ??C. CaF2 increased the diffusivity by a factor of 3 to 5 while MnOx and FeOx, ilmenite and TiO 2 increased the diffusivity substantially and SiO2 had an opposite effect. The measured diffusivities are in accord with published data on comparable systems and are discussed with reference to Eyring theory. It was concluded that MnOx, FeOx and ilmenite in the slag increase the dissolution rate and diffusivity of lime, showing comparable results with respect to CaF2.
| Identifer | oai:union.ndltd.org:ADTP/277421 |
| Date | January 2005 |
| Creators | Haji Amini, Shahriar, School of Chemical Engineering & Industrial Chemistry, UNSW |
| Publisher | Awarded by:University of New South Wales. School of Chemical Engineering and Industrial Chemistry |
| Source Sets | Australiasian Digital Theses Program |
| Language | English |
| Detected Language | English |
| Rights | Copyright Shahriar Haji Amini, http://unsworks.unsw.edu.au/copyright |
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