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Raman and NMR Investigation of Molecular Reorientation and Internal Rotation in Liquids

Molecular rotational motions are known to influence both Raman scattering of light and nuclear spin relaxation. Therefore, the application of Raman bandshape analysis and NMR relaxation time measurements to probe molecular dynamics in liquids will provide us with a deeper understanding of the dynamical behavior and structure of molecules in the liquid phase. Presented here are (i) studies of molecular reorientation of acetonitrile in the neat liquid phase and in solution by Raman bandshape analysis and NMR relaxation; (ii) studies of reorientational dynamics and internal rotation in transition metal clusters by NMR relaxation.

Identiferoai:union.ndltd.org:unt.edu/info:ark/67531/metadc278558
Date12 1900
CreatorsYuan, Peng
ContributorsDesiderato, Robert, Schwartz, Martin, Marshall, Paul, 1960-, Acree, William E. (William Eugene), Brady, William Thomas, Roberts, James A.
PublisherUniversity of North Texas
Source SetsUniversity of North Texas
LanguageEnglish
Detected LanguageEnglish
TypeThesis or Dissertation
Formatvii, 161 leaves: ill., Text
RightsPublic, Copyright, Copyright is held by the author, unless otherwise noted. All rights reserved., Yuan, Peng

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