Waste is commonly disposed in landfills, this result in the formation of leachate which
needs to be treated to acceptable standards before being discharged to the environment.
High concentrations of pollutants, particularly ammonia, in the landfill leachate are
persistent even after the closure of the landfill and it requires ad hoc treatment. Treated
leachate can still be characterized by high concentrations of nitrates, which exceeds the
discharge standards. This phenomenon is observed in the Mariannhill landfill site in
Durban, where leachate is nitrified in a Sequencing batch reactor and produces effluent
with over 1000 mg/l (Trois et al, 2010a). Denitrification can be used to remove nitrate
concentrations, this process occurs under anoxic conditions in the presence of an external
carbon source.
Denitrification treatment methods utilize chemicals such as methanol and ethanol as
carbon sources, but the large scale application of these chemicals is often uneconomical.
This research aims at identifying the cost effective treatment system for bio-denitrification
that utilizes commercial garden refuse (CGR raw and lightly composted for 10 weeks
“CGR 10”) as carbon sources. The feasibility checks for applying these substrates were
based on the efficiency and kinetics of nitrate removal over a short and long-term period,
thus providing the estimates for operational procedures. Initial characterization tests, batch
and column tests were performed in the lab towards achieving the aim of this research.
All batch tests achieved 100% of nitrate removal, but CGR raw was faster than CGR 10
with a time difference of 16% and 20% for batches at 100 and 500 mg/L, respectively. The
significant difference in the kinetic removal efficiency was observed in batch tests at 2000
mg/L, where CGR raw was about 18 times faster than CGR 10 and about 2 times faster
than that of CGR raw at 500 mg/L. Thus, the kinetics of nitrate removal in CGR raw at
2000 mg/L was suspected to be due to chemical reaction other than biological reaction. In
the second set of batch tests the kinetics of nitrate removal for CGR raw was about 3
times that of CGR 10.
The column tests, which were operated as continuous flow reactor did not achieve full
denitrification due to high flow rate applied. First set of column tests (columns A) used
previously used substrates to treat synthetic nitrate solution (500 and 2000 mg/L). Second
set of column tests (columns B) used fresh substrates to treat pre-treated landfill leachate
with nitrate concentration of about 2000 mg/L. CGR 10 achieved better removal efficiency
than CGR raw when treating synthetic solution. Whereas, CGR raw achieved better nitrate
removal when treating pre-treated landfill leachate. Decrease in flow rate improved the
removal efficiency of the substrates. Dilution of nitrified leachate to about 500 mg/L could
improve the efficiency of the substrates. / Thesis (M.Sc.Eng.)-University of KwaZulu-Natal, Durban, 2011.
| Identifer | oai:union.ndltd.org:netd.ac.za/oai:union.ndltd.org:ukzn/oai:http://researchspace.ukzn.ac.za:10413/9599 |
| Date | 23 September 2013 |
| Creators | Zondi, Mzamoyendoda Samuel. |
| Contributors | Trois, Cristina. |
| Source Sets | South African National ETD Portal |
| Language | en_ZA |
| Detected Language | English |
| Type | Thesis |
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