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High Temperature Enthalpies of the Lead Halides: Enthalpies and Entropies of Fusion

The objectives of this investigation were: 1. To establish calorimetrically the transition temperature for the orthorhombic to cubic transition exhibited by PbF₂ and to determine the enthalpy of this transition. 2. To determine if the solid-solid phase transitions claimed in the literature for PbCl₂, PbF₂, PbBr₂, and PbI₂ were of thermodynamic importance, and if so, to determine the enthalpies of transition. 3. To determine if the discontinuous thermal expansions reported by Hsu for the lead halides were of thermodynamic importance. 4. To obtain reliable heat content data for the lead halides in both the solid and liquid states.

Identiferoai:union.ndltd.org:unt.edu/info:ark/67531/metadc164404
Date06 1900
CreatorsLinsey, Clarence W.
ContributorsEscue, Richard Byrd, Sybert, J. R., Gilbert, Robert A., Busey, R. H., Desiderato, Robert, Brady, William Thomas, Glaze, William
PublisherNorth Texas State University
Source SetsUniversity of North Texas
LanguageEnglish
Detected LanguageEnglish
TypeThesis or Dissertation
Formatvi, 103 leaves : ill., Text
RightsPublic, Copyright, Copyright is held by the author, unless otherwise noted. All rights reserved., Linsey, Clarence W.

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