Previous investigation of the kinetics and mechanism of the substitution reaction of bidentate substituted transition metal carbonyl complexes with Lewis bases (L') to yield the cis distributed bidentate substitution product, where M=Cr, Mo, or W and S-S = DTO (2,2,7,7-tetra-methyl-3, 6-dithiaoctane) or DTN (2,2,8,8-tetramethyl-3,7-dithianonane) have suggested that this reaction proceeds via a mechanism involving initial reversible dissociation of one end of the bidentate sulfur ligand followed by rapid attack of L' on the resulting five-coordinate intermediate.
| Identifer | oai:union.ndltd.org:unt.edu/info:ark/67531/metadc332637 |
| Date | 12 1900 |
| Creators | Schultz, Linda D. |
| Publisher | North Texas State University |
| Source Sets | University of North Texas |
| Language | English |
| Detected Language | English |
| Type | Thesis or Dissertation |
| Format | Text |
| Rights | Public, ..., Copyright, Copyright is held by the author, unless otherwise noted. All rights reserved. |
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