Molecular rotational motions are known to influence both Raman scattering of light and nuclear spin relaxation. Therefore, the application of Raman bandshape analysis and NMR relaxation time measurements to probe molecular dynamics in liquids will provide us with a deeper understanding of the dynamical behavior and structure of molecules in the liquid phase. Presented here are (i) studies of molecular reorientation of acetonitrile in the neat liquid phase and in solution by Raman bandshape analysis and NMR relaxation; (ii) studies of reorientational dynamics and internal rotation in transition metal clusters by NMR relaxation.
| Identifer | oai:union.ndltd.org:unt.edu/info:ark/67531/metadc278558 |
| Date | 12 1900 |
| Creators | Yuan, Peng |
| Contributors | Desiderato, Robert, Schwartz, Martin, Marshall, Paul, 1960-, Acree, William E. (William Eugene), Brady, William Thomas, Roberts, James A. |
| Publisher | University of North Texas |
| Source Sets | University of North Texas |
| Language | English |
| Detected Language | English |
| Type | Thesis or Dissertation |
| Format | vii, 161 leaves: ill., Text |
| Rights | Public, Copyright, Copyright is held by the author, unless otherwise noted. All rights reserved., Yuan, Peng |
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