Large specific gravimetric/volumetric energy density, environmental benignity and safe low working voltage. All of these points have been used to describe the lithium sulfur (Li-S) battery in the past, but often times it is short cycle life and poor capacity retention that is associated with the Li-S battery. In order to realize the full potential of the Li-S battery in society today, many obstacles must be overcome. In a typical Li-S cell with an organic liquid electrolyte sulfur is reduced by lithium during discharge and subsequent lithium polysulfide species (Li2Sx where x, 2 < x < 8) are formed. These species are readily soluble in typical organic electrolytes and can lead to low Coulombic efficiency and most challenging: active mass loss. Through the loss of active mass, rapid capacity fading occurs over long-term cell cycling. Overcoming the loss of active mass and stabilizing cell capacity at high rates is pivotal to the realization of practical Li-S cells. In this thesis, four separate concepts and materials were studied and prepared with the aim to improve the Li-S batteries capacity, cycle life and capacity retention.
| Identifer | oai:union.ndltd.org:LACETR/oai:collectionscanada.gc.ca:OWTU.10012/7408 |
| Date | January 2013 |
| Creators | Evers, Scott Randall |
| Source Sets | Library and Archives Canada ETDs Repository / Centre d'archives des thèses électroniques de Bibliothèque et Archives Canada |
| Language | English |
| Detected Language | English |
| Type | Thesis or Dissertation |
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