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Manganese(III) acetate catalyzed allylic oxidation.

Su Pak Lee. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2005. / Includes bibliographical references (leaves 79-84). / Abstracts in English and Chinese. / Table of Contents --- p.i / Acknowledgement --- p.iii / Abstract --- p.iv / Abbreviation --- p.vi / Chapter 1. --- Introduction --- p.1 / Chapter 1.1 --- General Background --- p.1 / Chapter 1.2 --- Stoichiometric Oxidant --- p.4 / Chapter 1.2.1 --- Chromium Trioxide-pyridine --- p.5 / Chapter 1.2.2 --- "Chromium Trioxide-3,5-dimethylpyrazole" --- p.6 / Chapter 1.3 --- Catalytic Allylic Oxidation --- p.8 / Chapter 1.3.1 --- Homogeneous Catalysts --- p.8 / Chapter 1.3.1.1 --- Chromium Catalysts --- p.8 / Chapter 1.3.1.2 --- Iron Catalysts --- p.11 / Chapter 1.3.1.3 --- Copper Catalysts --- p.13 / Chapter 1.3.1.4 --- Palladium Catalysts --- p.14 / Chapter 1.3.1.5 --- Rhodium Catalysts --- p.19 / Chapter 1.3.2 --- Heterogeneous Catalysts --- p.22 / Chapter 1.4 --- Manganese(III) Acetate --- p.24 / Chapter 1.5 --- General Application of Manganese(III) Acetate --- p.25 / Chapter 1.5.1 --- Oxidative Free Radical Cyclization --- p.25 / Chapter 1.5.2 --- α-Acetoxylation --- p.27 / Chapter 1.6 --- Manganese(III) Catalyzed Reactions --- p.28 / Chapter 1.6.1 --- Epoxidation --- p.28 / Chapter 1.6.2 --- Sulfur oxidation --- p.29 / Chapter 2. --- Results and Discussions --- p.31 / Chapter 2.1 --- The Scope --- p.31 / Chapter 2.2 --- Tuning of Reaction Conditions --- p.32 / Chapter 2.2.1 --- Variation of Oxidant --- p.32 / Chapter 2.2.2 --- Variation of the Amount of Oxidant and Catalyst --- p.34 / Chapter 2.2.3 --- Variation of Solvent --- p.36 / Chapter 2.3 --- Results of Allylic Oxidation under Optimized Conditions --- p.39 / Chapter 2.4 --- Modification of Manganese(III) Acetate Catalysed Allylic Oxidation --- p.46 / Chapter 2.4.1 --- By Adding Base --- p.46 / Chapter 2.4.2 --- Assistance by Oxygen --- p.49 / Chapter 2.5 --- Mechanism --- p.53 / Chapter 3. --- Conclusion --- p.60 / Chapter 4. --- Experimental Section --- p.62 / Chapter 5. --- References --- p.79 / Chapter 6. --- Appendix --- p.85

Identiferoai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_325381
Date January 2005
ContributorsSu, Pak Lee., Chinese University of Hong Kong Graduate School. Division of Chemistry.
Source SetsThe Chinese University of Hong Kong
LanguageEnglish, Chinese
Detected LanguageEnglish
TypeText, bibliography
Formatprint, viii, 85 leaves : ill. ; 30 cm.
RightsUse of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/)

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