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Development and tribological characterisation of magnetron sputtered TiB<sub>2</sub> and Cr/CrN coatings

<p>The aim of this thesis was to develop wear resistant physical vapour deposited coatings of TiB<sub>2</sub> as well as multilayers of Cr/CrN. The correlation between deposition parameters and fundamental coating properties such as microstructure, composition, residual stress and hardness has been investigated. Finally, the influence of these properties on the coating behaviour in tribological applications has been evaluated.</p><p>It is shown that the use of electron bombardment of the growing coating during d.c. magnetron sputtering is beneficial for the growth of superhard TiB<sub>2</sub> coatings. Furthermore, electron bombardment results in TiB<sub>2</sub> coatings with significantly lower residual stresses than coatings deposited using ion bombardment. The low stresses in these coatings open up the possibility to deposit thicker PVD coatings, as confirmed in this thesis.</p><p>In addition, the use of TiB<sub>2</sub> coatings in tribological contacts against aluminium proved to be superior to many other commercial coatings used today, with respect to wear resistance, anti galling properties and a low friction.</p><p>Finally, a model is proposed which explains the observation that the abrasive wear resistance of multilayered Cr/CrN coatings can outperform that of the individual constituents. The model was found to satisfactory predict experimental data.</p>

Identiferoai:union.ndltd.org:UPSALLA/oai:DiVA.org:uu-635
Date January 2001
CreatorsBerger, Mattias
PublisherUppsala University, Department of Materials Science, Uppsala : Acta Universitatis Upsaliensis
Source SetsDiVA Archive at Upsalla University
LanguageEnglish
Detected LanguageEnglish
TypeDoctoral thesis, comprehensive summary, text
RelationComprehensive Summaries of Uppsala Dissertations from the Faculty of Science and Technology, 1104-232X ; 619

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