Su Pak Lee. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2005. / Includes bibliographical references (leaves 79-84). / Abstracts in English and Chinese. / Table of Contents --- p.i / Acknowledgement --- p.iii / Abstract --- p.iv / Abbreviation --- p.vi / Chapter 1. --- Introduction --- p.1 / Chapter 1.1 --- General Background --- p.1 / Chapter 1.2 --- Stoichiometric Oxidant --- p.4 / Chapter 1.2.1 --- Chromium Trioxide-pyridine --- p.5 / Chapter 1.2.2 --- "Chromium Trioxide-3,5-dimethylpyrazole" --- p.6 / Chapter 1.3 --- Catalytic Allylic Oxidation --- p.8 / Chapter 1.3.1 --- Homogeneous Catalysts --- p.8 / Chapter 1.3.1.1 --- Chromium Catalysts --- p.8 / Chapter 1.3.1.2 --- Iron Catalysts --- p.11 / Chapter 1.3.1.3 --- Copper Catalysts --- p.13 / Chapter 1.3.1.4 --- Palladium Catalysts --- p.14 / Chapter 1.3.1.5 --- Rhodium Catalysts --- p.19 / Chapter 1.3.2 --- Heterogeneous Catalysts --- p.22 / Chapter 1.4 --- Manganese(III) Acetate --- p.24 / Chapter 1.5 --- General Application of Manganese(III) Acetate --- p.25 / Chapter 1.5.1 --- Oxidative Free Radical Cyclization --- p.25 / Chapter 1.5.2 --- α-Acetoxylation --- p.27 / Chapter 1.6 --- Manganese(III) Catalyzed Reactions --- p.28 / Chapter 1.6.1 --- Epoxidation --- p.28 / Chapter 1.6.2 --- Sulfur oxidation --- p.29 / Chapter 2. --- Results and Discussions --- p.31 / Chapter 2.1 --- The Scope --- p.31 / Chapter 2.2 --- Tuning of Reaction Conditions --- p.32 / Chapter 2.2.1 --- Variation of Oxidant --- p.32 / Chapter 2.2.2 --- Variation of the Amount of Oxidant and Catalyst --- p.34 / Chapter 2.2.3 --- Variation of Solvent --- p.36 / Chapter 2.3 --- Results of Allylic Oxidation under Optimized Conditions --- p.39 / Chapter 2.4 --- Modification of Manganese(III) Acetate Catalysed Allylic Oxidation --- p.46 / Chapter 2.4.1 --- By Adding Base --- p.46 / Chapter 2.4.2 --- Assistance by Oxygen --- p.49 / Chapter 2.5 --- Mechanism --- p.53 / Chapter 3. --- Conclusion --- p.60 / Chapter 4. --- Experimental Section --- p.62 / Chapter 5. --- References --- p.79 / Chapter 6. --- Appendix --- p.85
| Identifer | oai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_325381 |
| Date | January 2005 |
| Contributors | Su, Pak Lee., Chinese University of Hong Kong Graduate School. Division of Chemistry. |
| Source Sets | The Chinese University of Hong Kong |
| Language | English, Chinese |
| Detected Language | English |
| Type | Text, bibliography |
| Format | print, viii, 85 leaves : ill. ; 30 cm. |
| Rights | Use of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/) |
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