Arising from the discussion about a sustainable development of the energy sector, more and more interest of different industrial branches (e.g. in the automotive field or by the energy supply companies) is actually directed to the use of fuel cells. They show high degrees of ef-ficiency, little pollution and the ability of combined heat and power generation, and moreover they are modularly built. As a fuel they need hydrogen, but the infrastructure of its supply is much worse than necessary. So, at least for a time of transition, hydrogen must be produced from hydrocarbon fuels. A new idea is the hydrogen production from liquid higher hydrocar-bon compositions, as diesel fuel, in a catalytic cracker. This diesel processor is based on a technology developed by the University of Essen-Duisburg at Duisburg. Liquid higher hydrocarbons, as diesel, also contain different sulfur compounds. The aim of this work was to gain knowledge about the influence of sulfur to a complete catalytic cracker system. The study consists of two parts, the first dealing with the influence of sulfur com-pounds to the catalytic cracker itself, and the second with the influence of the products of the reaction of sulfur compounds flowing with the resultant gas into the low-temperature Polymer Electrolyte Membrane Fuel Cell, PEMFC. In the catalytic cracker the influence of sulfur on the activity and the hydrogen selectivity of catalysts of two different precious metals used separately as well as in mixture is investi-gated. Furthermore, the catalysts stability under the cracking temperature of nearly 1,200 K is tested. As an example, the effect of sulfur-containing fuel to a PEMFC is shown and analysed. Moreover, a mathematical-physical model is developed, describing the effects of the degra-dation of a PEMFC by sulfur contamination. Finally, the efficiency of a desulfurizing unit, pre-connected to the fuel cell to extend its lifetime, is investigated.
| Identifer | oai:union.ndltd.org:DUETT/oai:DUETT:duett-09192005-102928 |
| Date | 19 September 2005 |
| Creators | Benz, Wolfgang |
| Contributors | Prof. Dr. rer. nat. Angelika Heinzel, Prof. Dr. rer. nat. Jan Dirk Herbell |
| Publisher | Gerhard-Mercator-Universitaet Duisburg |
| Source Sets | Dissertations and other Documents of the Gerhard-Mercator-University Duisburg |
| Language | German |
| Detected Language | English |
| Type | text |
| Format | application/pdf, text/html |
| Source | http://www.ub.uni-duisburg.de/ETD-db/theses/available/duett-09192005-102928/ |
| Rights | unrestricted, I hereby certify that, if appropriate, I have obtained and attached hereto a written permission statement from the owner(s) of each third party copyrighted matter to be included in my thesis, dissertation, or project report, allowing distribution as specified below. I certify that the version I submitted is the same as that approved by my advisory committee. Hiermit erteile ich der Universitaet Duisburg das nicht-ausschliessliche Recht unter den unten angegebenen Bedingungen, meine Dissertation, Staatsexamens- oder Diplomarbeit, meinen Forschungs- oder Projektbericht zu veroeffentlichen und zu archivieren. Ich behalte das Urheberrecht und das Recht das Dokument zu veroeffentlichen und in anderen Arbeiten weiterzuverwenden. |
Page generated in 0.0017 seconds