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Microstructural effects on capacity-rate performance of vanadium oxide cathodes in lithium-ion batteries

Thesis (S.B.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, 2005. / Includes bibliographical references (leaf 29). / Vanadium oxide thin film cathodes were analyzed to determine whether smaller average grain size and/or a narrower average grain size distribution affects the capacity-rate performance in lithium-ion batteries. Vanadium oxide thin films were prepared by sputtering onto ITO-coated glass substrates and crystallized in a refined annealing process to generate diverse microstructures. Average grain size and grain size distribution were determined in SEM analysis. No significant difference was observed in capacity rate behavior with changes in microstructure. However, it is speculated that further in situ analysis may show different relative diffusion rates into grains of differing sizes is related to different microstructures. / by Robin M. Davis. / S.B.

Identiferoai:union.ndltd.org:MIT/oai:dspace.mit.edu:1721.1/32852
Date January 2005
CreatorsDavis, Robin M. (Robin Manes)
ContributorsDonald R. Sadoway., Massachusetts Institute of Technology. Dept. of Materials Science and Engineering., Massachusetts Institute of Technology. Dept. of Materials Science and Engineering.
PublisherMassachusetts Institute of Technology
Source SetsM.I.T. Theses and Dissertation
LanguageEnglish
Detected LanguageEnglish
TypeThesis
Format29 leaves, 1359675 bytes, 1358337 bytes, application/pdf, application/pdf, application/pdf
RightsM.I.T. theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission. See provided URL for inquiries about permission., http://dspace.mit.edu/handle/1721.1/7582

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