Submitted by Celso Magalhaes (celsomagalhaes@ufrrj.br) on 2018-04-04T13:50:36Z
No. of bitstreams: 1
2017 - Guilherme Raymundo Sa.pdf: 3173899 bytes, checksum: 9c3276f740106907243c1c187bbc9d77 (MD5) / Made available in DSpace on 2018-04-04T13:50:36Z (GMT). No. of bitstreams: 1
2017 - Guilherme Raymundo Sa.pdf: 3173899 bytes, checksum: 9c3276f740106907243c1c187bbc9d77 (MD5)
Previous issue date: 2017-08-28 / Zeolites are microporous aluminosilicates and have assumed the position of most important catalysts in the chemical industry. However, these microporous materials have the limitation of the diffusion of molecules with larger kinetic diameter. Hybrid materials with hierarchical arrangement of pores in the micro-mesoporous scale have attracted great attention and interest in the last decades because they present acidic activity similar to the microporous zeolites and ordered pore diameter of the mesoporous materials. Beta zeolite can be used in a number of applications, including refining, petrochemical and biomass. The generation of mesopores in the beta zeolite enables higher yields by improving mass transfer in the FCC process. In this work, samples of the mesoporous material SBA-15 were synthesized and used as a source of silica for the synthesis of the mesoporous beta zeolite using the Dry Gel Conversion (DGC) technique. Samples of SBA-15 were submitted to three carbonization methods, using as carbon source sucrose, the organic template and both, in order to fill their pores with carbonaceous material and to prevent the collapse of its structure. The aluminization samples were studied at two times, before and during the dry gel synthesis. Three crystallization times were studied. X-ray diffraction (XRD), N2 adsorption / desorption, nuclear magnetic resonance (NMR), scanning electron microscopy (SEM) and infrared absorption spectroscopy with Fourier transform (FTIR) were used to characterize the samples. The results indicated that there was formation of zeolite beta presenting mesoporosity for the carbonization method that used only the template as carbon source. These samples showed BEA crystalline structure confirmed by XRD and FTIR analysis and formation of isotherms with type I and IV characteristics, with BET area greater than 500 m? / g, a volume of micropores close to 0.20 cm3 / g and with a volume of mesopores greater than 0.15 cm 3 / g. The other carbonization methods formed an amorphous phase, materials with low crystallinity and formation of polymorphs B and C over polymorph A. The samples presented the formation of mesoporosity did not present the mesopores present in the SBA-15, indicating collapse of the structure during the process of dry gel conversion / Ze?litas s?o aluminossilicatos microporosos e assumiram a posi??o de catalisadores mais importantes na ind?stria qu?mica. Entretanto, esses materiais microporosos possuem a limita??o da difus?o de mol?culas com di?metro cin?tico maior. Os materiais h?bridos com arranjo hier?rquico de poros na escala micro-mesoporosa atra?ram grande aten??o e interesses nas ?ltimas d?cadas pois apresentam atividade ?cida similar ?s ze?litas microporosas e di?metro de poros ordenados dos materiais mesoporosos. A ze?lita Beta pode ser usada em diversas aplica??es, incluindo o refino, a petroqu?mica e o processamento de biomassa. A gera??o de mesoporos na ze?lita beta possibilita maior rendimento melhorando a transfer?ncia de massa no processo de FCC. Neste trabalho foram sintetizadas amostras do material mesoporoso SBA-15 e utilizadas como fonte de s?lica para a s?ntese da ze?lita beta mesoporosa em meio seco utilizando a t?cnica de Dry Gel Conversion (DGC). As amostras de SBA-15 foram submetidas a tr?s m?todos de carboniza??o, utilizando como fonte de carbono sacarose, o direcionador de estrutura e ambos, com o objetivo de preencher seus poros com material carbon?ceo e evitar o colapso de sua estrutura. A aluminiza??o das amostras foi estudada em dois momentos, antes e durante a s?ntese do gel seco. Foram estudados tr?s tempos de cristaliza??o. Para caracteriza??o das amostras foram utilizadas as t?cnicas de difra??o de raios-X (DRX), adsor??o/dessor??o de N2, resson?ncia magn?tica nuclear (RMN), microscopia eletr?nica de varredura (MEV) e espectroscopia de absor??o no infra vermelho com transformada de Fourier (FTIR). Os resultados indicaram que houve a forma??o de ze?lita beta apresentando mesoporosidade para o m?todo de carboniza??o que utilizou apenas o direcionador de estrutura como fonte de carbono. Estas amostras apresentaram estrutura cristalina BEA confirmado pelas an?lises de DRX e FTIR e forma??o de isotermas com caracter?sticas do tipo I e IV, com ?rea BET superior a 500m?/g, um volume de microporos pr?ximos de 0,20 cm3/g e com um volume de mesoporos superior a 0,15 cm3/g. Os demais m?todos de carboniza??o formaram uma fase amorfa, materiais de baixa cristalinidade e com forma??o dos polimorfos B e C em detrimento ao polimorfo A. Os melhores resultados foram obtidos com o tempo de cristaliza??o de 48 horas. As amostras apresentando a forma??o de mesoporosidade n?o apresentaram os mes n?o apresentaram os mes n?o apresentaram os mesn?o apresentaram os mes n?o apresentaram os mesn?o apresentaram os mes n?o apresentaram os mes n?o apresentaram os mesn?o apresentaram os mes n?o apresentaram os mes n?o apresentaram os mes oporos presentes na SBA oporos presentes na SBA oporos presentes na SBA oporos presentes na SBA oporos presentes na SBA oporos presentes na SBA oporos presentes na SBAoporos presentes na SBAoporos presentes na SBAoporos presentes na SBA-15, indicando colapso da 15, indicando colapso da 15, indicando colapso da 15, indicando colapso da 15, indicando colapso da 15, indicando colapso da 15, indicando colapso da 15, indicando colapso da 15, indicando colapso da estrutura estrutura estrutura durante o processo de s?ntese seca
| Identifer | oai:union.ndltd.org:IBICT/oai:localhost:jspui/2245 |
| Date | 28 August 2017 |
| Creators | S?, Guilherme Raymundo |
| Contributors | Fernandes, Lindoval Domiciano, Gaspar, Alexandre Barros, Augusto, Bruno Lobato |
| Publisher | Universidade Federal Rural do Rio de Janeiro, Programa de P?s-Gradua??o em Engenharia Qu?mica, UFRRJ, Brasil, Instituto de Tecnologia |
| Source Sets | IBICT Brazilian ETDs |
| Language | Portuguese |
| Detected Language | English |
| Type | info:eu-repo/semantics/publishedVersion, info:eu-repo/semantics/masterThesis |
| Format | application/pdf |
| Source | reponame:Biblioteca Digital de Teses e Dissertações da UFRRJ, instname:Universidade Federal Rural do Rio de Janeiro, instacron:UFRRJ |
| Rights | info:eu-repo/semantics/openAccess |
| Relation | AGUADO, J.; SERRANO, D. P.; RODR?GUEZ, J. M. Zeolite Beta with hierarchical porosity prepared from organofunctionalized seeds. Microporous and Mesoporous Materials, v. 115, v.3, p. 504?513, 2008. ALMEIDA, N. C. DE. S?ntese de faujasita mesoporosa por s?ntese direta utilizando softtemplate, Disserta??o (Mestrado), UFRRJ, 2017. ANJOS, W. L., S?ntese e caracteriza??o da peneira molecular SAPO-34 para rea??o de obten??o de olefinas leves a partir de metanol.Unicamp, Campinas, SP, 2011. B?RCIA, P. S.; SILVA, J. A. C.; RODRIGUES, A. E. Separation by Fixed-Bed Adsorption of Hexane Isomers in Zeolite BETA Pellets. Industrial & Engineering Chemistry Research., v. 45, n. 12, p. 4316-4328, 2006. BARRER, R. M. , P. J. DENNY and E. M. FLANIGEN, U.S. Patent 3, 306, 922, 1962. BEKKUM, H. V., FLANIGEM, E. M., JANSEN, J. C. Introduction to zeolite science and practice. Amsterdam: Elsever Science Publishers BV, 754 p,1991. BENVINDO, F. S., S?ntese e caracteriza??o de peneiras moleculares do tipo SAPO-34 e MeAPSO-34 / Fernanda Soares Benvindo. Disserta??o de mestrado. UFRRJ? 2006. BRAGA, A. A., MORGON, N. H. Descri??es estruturais cristalinas de ze?litos. Qu?mica Nova, v.30, n.1, p. 178-188, Agosto 2007. BRECK D. W. e ACARA, N. A. U.S. Patent 2, 950, 952, 1960. BRECK, D. W. , EVERSOLE, W. G. e MILTON, R. M. Journal of the American Chemical Society.78, 2338. 1956. BRECK, D. W. Zeolite Molecular Sieves: Structure, Chemistry and Use. Malabar: Robert E. Krieger Publishing Company, 1984. BRUNAUER, STEPHEN, EMMETT, P. H., TELLER, EDWARD. Adsorption of Gases in Multimolecular Layers. Journal of the American Chemical Society, v. 60, n.2, p. 309-319, February 1938. CABRAL, R.P.B. S?ntese e Avalia??o de NiMo/Beta e NiMo/SAPO-5 no hidrocraqueamento do cumeno com piridina. 2008. 247f. Tese (Doutorado em Engenharia de Processos) ? Programa e P?s-Gradua??o em Engenharia de Processos, Universidade Federal de Campina Grande, Campina Grande, PB, 2008. CALDEIRA, V. P. da S. S?ntese e caracteriza??o de ze?lita beta hierarquizada e materiais h?bridos micro-mesoporosos aplicados no craqueamento de PEAD.Tese (Doutorado em Qu?mica) , Natal, RN, 2013. 59 CAMBLOR, M. A., A. MISUD, C. A., PEREZ-PARIENTE, J., VALENCIA, S. Synthesis of nanocrystalline zeolite beta in the absence of alkali metal cations p. 341-348 in: Progress in Zeolite and Microporous Materials, Preceedings of the 11th International Zeolite Conference. Studies in Surface Science and Catalysis, Microporous Materials. Seoul, Korea v.105, p. 3-2385, 1997. CAMBLOR, M. A., CORMA, A., VALENCIA, S. Characterization of nanocrystalline zeolite Beta, Microporous and Mesoporous Materials, v.25, p. 59, 1998. CAMPOS, A.A.; DIMITROV, C.R. da SILVA, M. WALLAU, E.A. URQUIETA-GONZ?LEZ Microporous and Mesoporous Materials Vol. 95, P 92?103. 2006. CARVALHO, D. R. Prepara??o de ze?lita beta nanoestruturada atrav?s da funcionaliza??o de sementes com organossilanos. UFBA, Salvador 2012. CEJKA, J. Recent trends in the Synthesis of molecular sieves. Studies in Surface Science and Catalysis, 157, p. 111, 2005. ?EJKA, J.; CENTI, G.; PEREZ-PARIENTE, J.; ROTH, W.J. Zeolite-based materials for novel catalytic applications: Opportunities, perspectives and open problems. Catalysis Today, v.179, p.2-15, 2012. CHEN, B.; C. W. KIRBY, e Y. HUANG Investigation of Crystallization of Molecular Sieve AlPO4-5 by the Dry Gel Conversion Method.The Journal of Physical Chemistry. 113, 15868?15876. 2009. CIESLA, U., SCHUTH, F., S?ntese de Peneiras Moleculares Mesoporosas MCM-41 em Meio Fluor?drico. Ordered mesoporous materials. Microporous and Mesopourous Materials, v. 27, p.131-149, 1999. CORMA, A., From microporous to mesoporous molecular sieve materials and thei use in catalysis. Chemical Reviews, vol. 97, p.2373-2419, 1997. CORMA, A.; FORN?S, V.; MELO, F.; P?REZ-PARIENTE, J. Zeolite Beta: Structure, Activity, and Selectivity for Catalytic Cracking. American Chemical Society. Symposium Series, v. 375, p. 49-63, 1988. CORMA, A.; FORN?S, V.; MONT?N, J.B.; ORCHILL?S, V. Catalytic Activity of largepore high Si/Al zeolites: Cracking of heptane on H-Beta and dealuminated HY zeolites. Journal of Catalysis, v. 107, p.288-295, 1987. CORMA, A; M MOLINER,M; CANT?N, A J; D?AZ-CABA?AS, M J; JORD?, J L; ZHANG, D SUN; J JANSSON, K; HOVM?LLER S e ZOU, X. Chemistry of Materials., 20 (9), pp 3218?3223, 2008. COSTA, M.J.F.; ARAUJO, A.S.; SILVA, E.F.B.; FARIAS, M.F.; FERNANDES JR, V.J.; SANTA-CRUZ, P.A.; PACHECO, J.G.A. Model-free kinetics applied for the removal of CTMA+ and TPA+ of the nanostructured hy-brid AlMCM-41/ZSM-5 material. Journal of Thermal Analysis and Calorimetry. v.106, p. 767?771, 2011. 60 DE BOER, J. H.; LIPPENS, B. C.; LINSEN, B. G.; BROEKHOFF, J. C. P.; VAN DEN HEUVEL, A.; OSINGA, T. V., Thet-curve of multimolecular N2-adsorption, Journal of Colloid and Interface Science. v. 21, n. 4, p. 405-414, 1966. DEBRAS, G., GOURGUE, A., NAGY, J. B., DE CLIPPELEIR, G. Physico-chemical characterization of pentasil type materials. I. Precursores and calcined zeolites. Zeolites, 5, p. 369, 1985. DINIZ, J.C., Substitui??o Isom?rfica de Sil?cio em Aluminofosfato com estrutura AEL. Disserta??o de mestrado. UFRN, Natal, 2000. ESTERMAN, M.; McCRUSKER, L.B.; BAERLOCHER, C.; MERROUCHE, A.; KESSLER, H. Nature 352, 320, 1991. FAN. J.; LEI, J.; WANG, L.; YU, C.; TU, B. and ZHAO, D.; Rapid and High-Capacity Immobilization of Enzymes Based on Mesoporous Silicas with Controlled Morphologies, Chem. Commun., p.2140, 2003. FECHETE, I.; WANGB Y.; V?DRINE, J. C., The past, present and future of heterogeneous catalysis, Catalysis Today, v. 189, p. 2? 27, 2012. FERN?NDEZ, M.A.C. S?ntesis de zeolita beta : est?dio de la substituici?n isom?rfica de Al y Si por Ga, Ge y Ti. 181f. Tese de Doutorado ?Instituto de Tecnologia Qu?mica (CSIC ? UPV), Universidad Autonoma de Madrid, Madrid, ES, 1992. FILHO, C. R. - Obten??o de ze?lita ? mesoporosa por s?ntese direta. Disserta??o (mestrado) ? Universidade Federal Rural do Rio de Janeiro, Curso de P?s-Gradua??o em Engenharia Qu?mica. 2011. FLANIGEN, E. M., Zeolites and Molecular Sieves: an Historical Perspective. Studies in Surface Science and Catalysis, v. 137, p. 11?35, 2001. GAAG, F. J. V. D., JANSEN J. C., BEKKUN, H. V. Template variation in the synthesis of zeolites ZSM-5. Applied Catalysis, 17, p. 261, 1985. GARC?A, R. A., SERRANO, D. P., OTERO D, Catalytic cracking of HDPE over hybrid zeolitic?mesoporous materials, Journal of Analytical and Applied Pyrolysis, v. 74, p. 379, 2005. GOLOMBOK, M. and BRUJIN, J., Catalysts for producing high octane-blending value olefins for gasoline. Applied Catalysis A: General 208, p. 47-53, 2001. GOMES, E. L. Influ?ncia do tamanho dos cristalitos da ze?lita ZSM-5 com raz?o Si/Al constante no desproporcionamento do etilbenzeno. Disserta??o de Mestrado, Universidade Federal de S?o Carlos, 199p. 1991. GON?ALVES, M.. L.. S?lidos micro-mesoestruturados tipo ze?lita ZSM-5/peneira molecular MCM-41 - s?ntese e estudo de propriedades. Disserta??o (Mestrado) S?o Carlos :UFSCar, 2006. 61 GROEN, J.C.; ABELL?, S.; VILLAESCUSA, L.A.; P?REZ-RAMIREZ, J. Mesoporous beta zeolite obtained by desilication. Microporous and Mesoporous Materials, v.144, p.93- 102, 2008. GROEN, J.C.; PEFFER, L.A.A.; MOULIJN, J.A.. P?REZ-RAMIREZ, J. On the introduction of intracrystalline mesoporosity in zeolites upon desilication in alkaline medium. Microporous and Mesoporous, v.69, p.29-34, 2004. GUIL, J. M.; GUIL-L?PEZ, R.; PERDIG?N-MEL?N, J. A.; CORMA, A. Determining the topology of zeolites by adsorption microcalorimetry of organic molecules. Microp. Mesop. Mater., v. 22 n. 1-3, p. 269-279, 1998. GUISNET, M.; RIBEIRO, F. R.; ?Ze?litos ? Um nanomundo ao servi?o da cat?lise? Funda??o Calouste Gulbenkian, Lisboa. p. 220 Janeiro 2004. GUO, W., XIONG, C., HUANG, L., LI, Q. Synthesis and characterization of composite molecular sieves comprising zeolite Beta with MCM-41 structures. J. Mater. Chem., 11, p. 1886, 2001. HABIB, S.F.; LAUNAY, M.; SPRINGUEL-HUET, F.; GUENNEAU , V.; SEMMER-HERL?DAN, N. N. TU?AR, V. KAU?I? e A. G?D?ON New J. Chem, 30, 1163-1170, 2006. HAN. S.; SOHN, K. and HYEON, T.; Fabrication of New Nanoporous Carbons Through Silica Templates and Their Application to the Adsorption of Bulky Dyes; Chem. Mater., v.12, n.11, p.3337?3341, 2000. HE, J. et al., Preparation and characterization of octyl-modified ordered mesoporous carbon CMK-3 for phenol adsorption, Microporous and Mesoporous Materials, v. 121, p. 173? 177, 2009. HO, S.; CHOU, T.C., The role of anion in the preparation of nickel catalyst detected by TPR and FT-IR spectra, Ind. Eng. Chem. Res., v. 34, n.7, p. 2279-2284, 1995. HOLM, M.S.; TAARNING, E.; EGEBLAD, K.; CHRISTENSEN, C.H. Catalysis with hierarchical zeolites. Catalysis Today, v.168, p.3-16, 2011. HU, D.,. XIA, Q.-H. LU, X.-H, LUO, X.-B.; LIU, Z.-M. Materials Research Bulletin 43 3553?3561, 2008. HUANG, L., GUO, W. DENG, P., XUE, Z., LI, Q. Investigation of synthesizing MCM-41 / ZSM-5 composites. J. Phys. Chem. B, 104, p. 2817, 2000. IUPAC ? Catalyst ? IUPAC Compendium of Chemical Terminology, Book section, v. 2291, p. 2293, 2014. IZA - International Zeolite Association. Structura databeses. Powder patterns. Dispon?vel em < http://www.iza-online.org/>Acessado em: 27/04/2016. 62 JOO, S. H.; JUN, S.; RYOO, R., Synthesis of ordered mesoporous carbon molecular sieves CMK-1, Microporous and Mesoporous Materials, v. 44, p. 153-158, 2001. JUN, S. et al., Synthesis of new nanoporous carbon with hexagonally ordered mesostructure, Journal of the American Chemical Society, v. 122, p. 10712?3, 2000. KANG, K.-K. AHN, W.-S. e RHEE, H.-K J Studies in Surface Scien. and Catalyst. vol.154 497, 2004 KATIYAR, A. and PINTO, N. G.; Visualization of Size-Selective Protein Separations on Spherical Mesoporous Silicates, Small, v.2, p.644, 2006. KIM, J.; LEE, J.; HYEON, T., Direct synthesis of uniform mesoporous carbons from the carbonization of as-synthesized silica/triblock copolymer nanocomposites, Carbon, v. 42, p. 2711?2719, 2004. KLOESTRA K.R,; BEKKUM, H. van ; JANSEN; J.C. Chem. Commun., p. 2281, 1997. KLOETSTRA, K.R.; ZANDBERGEN, H.W.; JANSEN, J.C.; VAN BEKKUM, H. Overgrowth of mesoporous MCM-41 on faujasite. Microporous Materials, v. 6, p. 287-293, 1996. KUMARAN, G. M., GARG, S., SONI, K., KUMAR, M., GUPTA, J. K., SHARMA, L. D., RAMA RAO, K. S., MURALI DHAR, G., Synthesis and characterization of acidic properties of Al-SBA-15 materials with varying Si/Al ratios. Microporous and Mesoporous Materials, vol. 114, pag.103-109, 2008. LIANG, X. et al., Synthesis and characterization of mesoporous Mn/Al-SBA-15 and its catalytic activity for NO reduction with ammonia, Catalysis Communications, v. 8, p. 1901?1904, 2007. LIN, S., SHI, L., RIBEIRO CARROT, M. M. L., CORROT, P. J. M., ROCHA, J., LI, M. R., ZOU, X. D., Direct synthesis without addition of acid of Al-SBA-15 with controllable porosity and high hydrothermal stability. Microporous and Mesoporous Materials, vol. 142, pag. 526?534, 2011. LINARES, M. Materiales zeol?ticos de elevada accesibilidad: propiedades catal?ticas en reacciones de qu?mica fina Tesis Doctoral, Departamento de Tecnolog?a Qu?mica y Ambiental, URJC, Madrid (2011). LUNA, F. J., SCHUCHARDT, U. Modifica??o de ze?litas para uso em cat?lise. Qu?mica Nova, v.24, n.6, p. 885-892, Mar?o 2001. MACBAIN, J.W., The Sorption of Gases And Vapors by Solids, Ruthedge & Sons, Londres 1932 apud D. W. Breck, Zeolite Molucular Sieves: Structure, Chemistry And Use, John Wiley & Sons, New York 1974. 63 MACEDO, J.L. Prepara??o e caracteriza??o de materiais com base zeol?tica para aplica??o em cat?lise., 2007. 144 f. Tese (Doutorado em Qu?mica) ? Instituto de Qu?mica, Universidade de Bras?lia, Bras?lia, DF. 2007. MART?NEZ, C.; VERBOEKEND, D.; P?REZ-RAM?REZ, J.; CORMA, A. Stabilized hierarchical USY zeolite catalysts for simultaneous increase in diesel and LPG olefinicity during catalytic cracking. Catalysis Science & Technology, v.3, p.972-981, 2013. MASCARENHAS, A. J. S., OLIVEIRA, E. C., PASTORE, H. O. Peneiras Moleculares: Selecionando as mol?culas por seu tamanho. Qu?mica Nova (edi??o especial).p. 25-34, Maio 2001. MATSUKATA, M. et al., Conversion of dry gel to microporous crystals in gas phase, Topics in Catalysis, v. 9, p. 77-92, 1999. MATSUKATA, M.; OSAKI, T.; OGURA, M.; KIKUCHI, E.Microporous and Mesoporous Materials 56 1?10, 2002. MATSUKATA, M. et al., Microporous Mesoporous Mater., 48, 23. 2001. MELO, A. C. R.. Craqueamento t?rmico e termocatal?tico do ?leo de girassol (Hellianthus annus L.) sobre materiais micro e mesoporosos. Tese (Doutorado em Qu?mica). Natal, RN, 2010. MEYNEN, V., COOL, P., VAANSANT, F., Verified syntheses of mesoporous materials. Microporous and Mesoporous Materials, Vol. 125, pag.170?223, 2009. MILTON, R. M.. U.S. Patent 2, 882, 243 (1959); U.S. Patent 2,882,244, 1959. NOTARI, B. Microporous Crystalline titanium silicates. Adv. Catal., 41, p. 253, 1996. OGURA, M., et al., A mechanistic study on the synthesis of MCM-22 from SBA-15 by dry gel conversion to form a micro- and mesoporous composite, Catalysis Today, v. 168, p. 118? 123, 2011. OGURA, M., et al., Formation of ZMM-n: The composite materials having both natures of zeolites and mesoporous silica materials, Microporous and Mesoporous Materials, v.101, p. 224?230, 2007. OGURA, M., et al., Preparation of zeolitic mesoporous aluminosilicate by vapor phase transport method, Studies in Surface and Catalysis, v. 158, p. 493-500, 2005. ON , D.T.; KALIGUINE, S.; Angew. Chem., 113, p. 3348, 2001. PACE, G.G.; REND?N, A.M.; FUENTES, G.R. Zeolitas: caracter?sticas, propiedades y aplicaciones industriales. 2. ed. Caracas: EdIT- Editora Innovaci?n Tecnol?gica, Facultad de Ingenier?a, UCV. 2000. 64 PARMENTIER, J., et al., New carbons with controlled nanoporosity obtained by nanocasting using a SBA-15 mesoporous silica host matrix and different preparation routes, Journal of Physics and Chemistry of Solids, v. 65, p. 139?146, 2004. PAYRA, P.; DUTTA, P. K., Zeolites: A Primer. In: Auerbach, S.M.M., Carraro, K. A., Dutta, P. K., Handbook Of Zoelite Science And Technology, Marcel Dekker Inc., p. 1-17, 2003. PERGHER, S. B. C. ; OLIVEIRA, L. C. A. ; SMANIOTTO, A. ; PETKOWICZ, D. I. Materiais magn?ticos baseados em diferentes ze?litas para remo??o de metais em ?gua. Quim. Nova, v. 28, n. 5, p. 751-755, 2005. RAO, P. R., LEON Y LEON, C. A., UEYAMA, K., & MATSUKATA, M. Synthesis of BEA by dry gel conversion and its characterization. Microporous and Mesoporous Materials, 21(4-6), 305-313. 1998. RODELLA, C.B. Prepara??o e caracteriza??o de catalisadores de V2O5 suportado em TiO2, Tese de Doutorado, USP, 2001. RYOO, R.; JOO, S.H. and JUN, S.; Synthesis of highly ordered carbon molecular sieves via template-modified structural transformation, J. Phys. Chem. B, p.103, n.37, p.7743?7746, 1999. SAMIEY, B.; C.H. CHENG e J. WU Materials , 7(2), 673-726, 2014. SANTOS, L. R. M. Preparo e avalia??o da ze?lita Beta mesoporosa para aplica??o em FCC. Tese (Doutorado em Tecnologia de Processos Qu?micos e Bioqu?micos) Rio de Janeiro: UFRJ/EQ, 2016. SAYARI, A., Periodic mesoporous materials: synthesis, characterization and potential applications, Stud. Surf. Sci. Catal., v. 102, p. 1-46, 1996. SEGOVIA, F. M. ? 1? Curso Iberoamericano sobre peneiras moleculares, CYTED, Ediciones Tecnicas Intevep, Caracas, Venezuela, p. 1-24, 1993. SENA, F. C. - S?ntese de peneira molecular mesoporosa AL-SBA-15 por diferentes rotas. Disserta??o (mestrado) ? Universidade Federal Rural do Rio de Janeiro, Curso de P?s-Gradua??o em Engenharia Qu?mica. 2012. SERRANO, D.P., GARC?A, R.A., VICENTE ,G., LINARES, M., PROCH?ZKOV?, D., C?EJKA, J. Acidic and catalytic properties of hierarchical zeolites and hybrid ordered mesoporous materials assembled from MFI protozeolitic units. Journal of Catalysis, v. 279, p. 366?380, 2011. SERRANO, D.P.; GARC?A, R.A.; OTERO, D. Friedel?Crafts acylation of anisole over hybrid zeolitic-mesostructured materials. Applied Catalysis A: General, v. 359, p. 69?78, 2009. SILVA, E. F. B., S?ntese, caracteriza??o e avalia??o catal?tica do silicoaluminofosfato SAPO-11 sulfatado, Disserta??o de mestrado, UFRN. Natal, 2008. 65 SKOOG, D. A. and LEARY, J. J., Principles of Instrumental Analysis, 4th Ed., aunders College Publishing, New York, 1992. SMART, L., MOORE, E. Solid State Chemistry, An Introduction. Londres: Chapman & Hall, p 407. 1992. SOUZA, B. F., SENA, F.C., FERNANDES, L. D., S?ntese e Caracteriza??o de Ze?lita Beta em Meio Seco. XXI SICAT. M?laga-Benalm?dena-Costa. Espa?a, 2008. SUN, J; ZHU, G; CHEN, Y; LI, J; WANG, L; PENG, Y; LI, H; QIU, S. Synthesis, surface and crystal structure investigation of the large zeolite beta crystal. Microporous and Mesoporous Materials. v.102, p. 242?248, 2007. SZCZODROWSKI, K., PR?LOT, B., LANTENOIS, S., DOUILLARD, J-M., ZAJAC, J., Effect of heteroatom doping on surface acidity and hydrophilicity of Al, Ti, Zr-doped mesoporous SBA-15. Microporous and Mesoporous Materials, vol. 124, pag. 84?93, 2009. SZOSTAK, R., Molecular Sieves Principles of Synthesis and Identification, Van Nostrand Reinhold, New York, 290, 1989. TAGUSHI, A.; SCHUTH, F.; Ordered mesoporous materials in catalysis, Microporous and Mesoporous Materials, v. 77, p. 1-45, 2005. TONG M, ZHANG D, FAN W, et al. Synthesis of chiral polymorph A-enriched zeolite Beta with an extremely concentrated fluoride route. Scientific Reports. 5:11521, 2015. VALENTE, T. D., S?ntese da mordenita a partir da Al-SBA-15.Disserta??o (mestrado) ? Universidade Federal Rural do Rio de Janeiro, Curso de P?s-Gradua??o em Engenharia Qu?mica, 2015. VAN DER WAAL, J. C., RIGUTTO, M. S., VAN BEKKUM H., Zeolite Titanium Beta: A selective catalyst for the gas-phase Meerwein?Ponndorf?Verley, and Oppenauer reactions, Chemical Communications, p.1241, 1994. VINU, A.,MURUGESAN, V.,B?HLMANN, W., HARTMANN, M., An Optimized Procedure for the Synthesis of AlSBA-15 with Large Pore Diameter and High Aluminum Content. J. Phys. Chem. B, vol. 108, pag. 11496-11505, 2004. WADLINGER, R. L. ; KERR, G. T. e ROSINSKI, E. J. US Patent 3,308,069, 1967. WADLINGER, R.L. et al., US Pat. 3375205, 1968. WEITKAMP, J., Zeolites and Catalysis. Solid State Ionics, v. 131, n. 1, p. 175?188, 2000. 91 XU, W.; J. DONG, J. LI, F. WU J. Chem. Soc., Chem. Commun. p. 755. 1990. ZAIDI, S. S. A. e ROHANI, S. Reviews in Chemical Engineering Vol. 21, No. 5, 2005 . ZHANG, H.; LI, Y. Preparation and characterization of Beta/MCM-41composite zeolite with a stepwise-distributed pore structure. Powder Technology, v.183, p. 73?78, 2008. 66 ZHAO, D.; J. FENG, Q. HUO, N. MELOSH, G.H. FREDRICKSON, B.F. CHMELKA, G.D. STUCKY, Science 279, 548. 1998. ZHAO, Y. X.; BAMWENDA, G. R.; GROTEN, W. A.; WOJCIECHOWSKI, B. W. The chain mechanism in catalytic cracking: the kinetics of 2-methylpentane cracking. Journal of Catalysis, v. 140, n. 1, p. 243-161, 1993. ZHIDOMIROV, G. M., et al. Molecular models of catalytically active sites in zeolites. Quantum chemical approach. Catalysis Today, v.51, p. 397-410, 1999. |
Page generated in 0.0119 seconds