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Previous issue date: 2010-08-21 / Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior / In this work the organosilanes aminopropyltriethoxysilane, 3-mercaptopropyltryethoxisilane and n[-3-(trimetoxisilyl)propyl]ethylenetriamine, as well as tetraethylortosilicate (TEOS), were employed to produce, by sol-gel method, organofuncionalized silicon samples. The
prepared samples were characterized by elementar analys by thermogravimetry and infrared spectroscopy. Those samples were employed to adsorb Cd2+, Pb2+, Ni2+ and Zn2+ from aqueous solutions (10, 20, 40, 60 and 80 mg L-1). In typical experiments, 50 mg of the organometrix was suspended in 20 mL of metal cation solutions at four different contact times: 30, 60, 90 and 120 minutes. The total amount of adsorbed cations were measured by atomic absorption spectrometry. To all investigated matrices, the following adsorption capacity was observed: Ni2+ > Zn2+ > Cd2+ > Pb2+. Such sequence is closely related with the
cation radius, as well as the cation hardness / No presente trabalho, cinco matrizes de s?lica organofuncionalizadas foram sintetizadas com os agentes sililantes aminopropiltrietoxisilano, 3-mercaptopropiltrietoxissilano e n[-3- (trimetoxissilil)propil]etilenotriamina. As matrizes h?bridas foram sintetizadas e caracterizadas por an?lise elementar, por an?lise t?rmica e espectroscopia na regi?o do infravermelho. Ap?s sua caracteriza??o as matrizes foram utilizadas como adsorventes para as esp?cies qu?micas Cd2+, Pb2+, Ni2+ e Zn2+ em solu??o aquosa. Para os testes utilizou-se 50 mg de cada matriz h?brada de s?lica-gel organofuncionalizada para adsor??o dos ?ons em solu??o aquosa com concentra??es de 10, 20, 40, 60 e 80 mg L-1. Os tempos de contato foram de 30, 60, 90 e 120 min, nos quais as misturas eram mantidas sob agita??o. Decorrido cada tempo, as concentra??es de equil?brio eram determinadas a partir de medidas de espectrometria de absor??o at?mica. A partir dessas medidas foi poss?vel determinar a quantidade de ?ons adsorvidos para cada um dos elementos em estudo e relacionar essas quantidades em rela??o ao tempo de contato e ao tipo de matriz. Para todas as matrizes investigadas seguiu-se a ordem de adsor??o: Ni2+ > Zn2+ > Cd2+ > Pb2+. A sequ?ncia de adsor??o ocorre de acordo como raio e dureza do c?tion
| Identifer | oai:union.ndltd.org:IBICT/oai:repositorio.ufrn.br:123456789/17622 |
| Date | 21 August 2010 |
| Creators | Cruz, ?ngela Maria Fagundes da |
| Contributors | CPF:31482015404, http://lattes.cnpq.br/2959800336802498, Oliveira, Otom Anselmo de, CPF:03936872449, http://lattes.cnpq.br/7903084274135177, Airoldi, Cl?udio, CPF:04517989887, http://lattes.cnpq.br/1481366755849386, Moura, Maria de F?tima Vit?ria de |
| Publisher | Universidade Federal do Rio Grande do Norte, Programa de P?s-Gradua??o em Qu?mica, UFRN, BR, F?sico-Qu?mica; Qu?mica |
| Source Sets | IBICT Brazilian ETDs |
| Language | Portuguese |
| Detected Language | Unknown |
| Type | info:eu-repo/semantics/publishedVersion, info:eu-repo/semantics/masterThesis |
| Format | application/pdf |
| Source | reponame:Repositório Institucional da UFRN, instname:Universidade Federal do Rio Grande do Norte, instacron:UFRN |
| Rights | info:eu-repo/semantics/openAccess |
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