Thesis advisor: Dunwei Wang / Metal organic frameworks (MOFs) are a class of compounds that show promising potential for a variety of applications due to their uniformity, highly porous structure, lack of dead volume, and fine-tunability. One of these significant applications is in selective ion transport, which makes MOF films a uniquely good separatory material for dual-electrolyte setups, such as those being investigated with Mg-Br batteries. This research has important environmental and industrial ramifications, considering the various drawbacks associated with commercially available batteries such as the lithium-ion battery. The MOF investigated was Mg-MOF-74, which showed promising selective Mg2+ transport abilities. Both Mg-MOF-74 powder and films were synthesized via a vapor-assisted conversion process to maximize efficiency. To characterize the MOF, XRD and SEM imaging was used. This allowed us to gain a nuanced understanding of the material and its properties for further applications. / Thesis (BA) — Boston College, 2022. / Submitted to: Boston College. College of Arts and Sciences. / Discipline: Departmental Honors. / Discipline: Chemistry.
| Identifer | oai:union.ndltd.org:BOSTON/oai:dlib.bc.edu:bc-ir_109512 |
| Date | January 2022 |
| Creators | Prostko, Gabriela |
| Publisher | Boston College |
| Source Sets | Boston College |
| Language | English |
| Detected Language | English |
| Type | Text, thesis |
| Format | electronic, application/pdf |
| Rights | Copyright is held by the author, with all rights reserved, unless otherwise noted. |
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