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The chemistry of low-valent late transition metal amides and amidinates.

by Tung Suet Lam. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2002. / Includes bibliographical references. / Abstracts in English and Chinese. / Table of Contents --- p.i / Acknowledgments --- p.iv / Abstract --- p.v / Abstract (Chinese version) --- p.vii / Abbreviations --- p.ix / List of Compounds --- p.xi / Chapter Chapter1. --- synthesis and structures of iron(ii) and cobalt(ii) complexes derived from pyridine-functionalized amido ligands / Chapter 1.1 --- INTRODUCTION --- p.1 / Chapter 1.1.1 --- General Background --- p.1 / Chapter 1.1.2 --- A Brief Review on Amides of the Late Transition Metals --- p.3 / Chapter 1.2 --- OBJECTIVES OF THIS WORK --- p.5 / Chapter 1.3 --- RESULTS AND DISCUSSION --- p.7 / Chapter 1.3.1 --- Alkali Metal Derivatives of N-Silylated 2-Aminopyridines --- p.7 / Chapter 1.3.1.a. --- "Synthesis of Aminopyridines [HN(SiMe3)》(2-C5H3N-6-R)] (R=H (1a), Me (1b)) and Their Lithium Derivatives" --- p.7 / Chapter 1.3.1.b. --- Synthesis of the Potassium Derivative [{K(L1)(tmeda)}2 ] (4) --- p.8 / Chapter 1.3.1.c. --- "Physical Characterization of Compounds 2a, 3 and" --- p.4 9 / Chapter 1.3.1.d. --- Molecular Structures of Compounds 3 and4 --- p.10 / Chapter 1.3.2 --- "Synthesis, Structures and Reactivities of Iron(II) and Cobalt(II) Amides" --- p.16 / Chapter 1.3.2.a. --- Synthesis of Mononuclear Iron(II) and Cobalt(II) Diamides --- p.16 / Chapter 1.3.2.b. --- Physical Characterization of Compounds 5-8 --- p.16 / Chapter 1.3.2.C. --- Molecular Structures of Compounds 5-8 --- p.17 / Chapter 1.4 --- EXPERIMENTAL FOR CHAPTER1 --- p.28 / Chapter 1.5 --- REFERENCES FOR CHAPTER1 --- p.31 / Chapter Chapter2. --- reaction of iron(II) and cobalt(II) amides with phenolic compounds / Chapter 2.1 --- "SYTHESIS, STRUCTURES AND REACTIVITIES OF IRON(II) AND COBALT(II) BIS(ARYLOXIDE)" --- p.36 / Chapter 2.1.a. --- "Reaction of Compounds 7 and 8 with 2,2 -ethylidenebis(4,6-di-tert-butyl phenol)" --- p.36 / Chapter 2.1.b. --- "Molecular Structures, Magnetic Moments, and Reactivities of Compounds 9and10" --- p.36 / Chapter 2.2 --- A GENERAL REVIEW ON CATECHOL DIOXYGENASES --- p.44 / Chapter 2.3 --- "SYTHESIS, STRUCTURES AND REACTIVITIES OF IRON(II) AND COBALT(II) CATECHOLATES" --- p.46 / Chapter 2.3.a. --- Synthesis of Binuclear Iron(II) and Cobalt(II) Catecholates --- p.46 / Chapter 2.3.b. --- Molecular Structures of Compounds 11 and12 --- p.48 / Chapter 2.3.c. --- Reactions of Compounds 11 and 12 with Dioxygen --- p.54 / Chapter 2.3.d. --- Identification of Oxidative Cleavage Products --- p.54 / Chapter 2.4 --- EXPERIMENTAL FOR CHAPTER2 --- p.56 / Chapter 2.5 --- REFERENCES FOR CHAPTER2 --- p.59 / Chapter Chapter3. --- synthesis of late transition metal amidinates / Chapter 3.1 --- INTRODUCTION --- p.62 / Chapter 3.1.1 --- General background --- p.62 / Chapter 3.1.1.a --- Metal´ؤAmidine Bonding Modes --- p.63 / Chapter 3.1.1.b. --- Preparation of Metal Amidinates Complexes --- p.64 / Chapter 3.1.2 --- "N-Silylated Benzamidinates of Li, Na and K 一 The Starting Materials" --- p.65 / Chapter 3.1.3 --- A General Review on The Chemistry of Low-Valent Late Transition- Metal Amidinates --- p.67 / Chapter 3.2 --- OBJECTIVES OF THIS WORK --- p.72 / Chapter 3.3 --- RESULTS AND DISCUSSION --- p.73 / Chapter 3.3.1 --- Synthesis and Structures of Lithium Benzamidinates --- p.73 / Chapter 3.3.1.a. --- "Synthesis of [Li(L3)(tmeda)] (L3 = [PhC(NSiMe3){N(2,6´ؤ Me2C6H3}]) and [Li(L4)(tmeda)] (L4 = [PyC(NSiMe3){N(2,6- Me2C6H3)}]) as Ligand´ؤTransfer Reagents" --- p.73 / Chapter 3.3.1.b. --- Physical Characterization of Compounds 15 and16 --- p.74 / Chapter 3.3.1.c. --- Molecular Structures of Compounds 15 and16 --- p.75 / Chapter 3.3.2 --- "Synthesis, Structures and Reactivities of Iron(II) and Cobalt(II) Amidinates" --- p.81 / Chapter 3.3.2.a. --- Synthesis of Mononuclear Iron(II) Benzamidinates --- p.81 / Chapter 3.3.2.b. --- Synthesis of a Binuclear Cobalt(II) Benzamidinate --- p.82 / Chapter 3.3.2.c. --- Physical Characterization of Compounds 17-19 --- p.83 / Chapter 3.3.2.d. --- Molecular Structures of Compounds 17-19 --- p.84 / Chapter 3.3.2.e. --- Reaction of Compound 18 with Dioxygen --- p.94 / Chapter 3.3.2.f. --- Molecular Structure of Compound20 --- p.95 / Chapter 3.3.3 --- Synthesis and Structures of Nickel(II) and Copper(I) Benzamidinates --- p.98 / Chapter 3.3.3.a --- Synthesis of a Nickel(II) Benzamidinate --- p.98 / Chapter 3.3.3.b. --- Synthesis of a Binuclear Copper(I) Benzamidinate --- p.99 / Chapter 3.3.3.c. --- Physical Characterization of Compounds 21 and22 --- p.101 / Chapter 3.3.3.d. --- Molecular Structures of Compounds 21 and22 --- p.102 / Chapter 3.3.4 --- Synthesis and Structures of Mononuclear Zinc(II) and Cadmium(II) Amidinates --- p.107 / Chapter 3.3.4.a --- Synthesis of Mononuclear Zinc(II) and Cadmium(II) Benzamidinates --- p.107 / Chapter 3.3.4.b. --- Physical Characterization of Compounds 23 and24 --- p.107 / Chapter 3.3.4.C. --- Molecular Structures of Compounds 23 and24 --- p.108 / Chapter 3.4 --- EXPERIMENTAL FOR CHAPTER3 --- p.113 / Chapter 3.5 --- REFERENCES FOR CHAPTER3 --- p.119 / appendix1 --- p.127 / appendix2 --- p.129

Identiferoai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_323874
Date January 2002
ContributorsLam, Tung Suet., Chinese University of Hong Kong Graduate School. Division of Chemistry.
Source SetsThe Chinese University of Hong Kong
LanguageEnglish, Chinese
Detected LanguageEnglish
TypeText, bibliography
Formatprint, xv, 138 leaves : ill. ; 30 cm.
RightsUse of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/)

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