Spray forming with eo-injection of a solid particulate phase to form a metal-metal composite has been studied as a new route for manufacture. Two Al-based matrices were investigated: AI-12Si for testing the feasibility of the new manufacturing route and Al-4Cu for providing better mechanical performance. For both composite types, Ti was chosen as the particulate phase and the processing-microstructure-property relationships then studied. At Peak Werkstoff GmbH, Germany 12 wt%Ti particles were eo-injected into an atomised Al alloy droplet spray and eo-deposited to form a rv300 kg billet. The microstructure comprised refined equiaxed a-AI grains (rv5fLm), spherical Si particles (rv5fLm) and uniformly distributed Ti particles (rv80fLm). Sections of the billet were extruded under a range of conditions into long strips 20mm wide and 6mm, 2.5mm and 1mm thickness. At high strains, the Ti particles were deformed into continuous fibres of a few microns in thickness. Accumulative roll bonding was then performed to higher total strains, while maintaining a constant cross-section, reducing the Ti fibres to sub-micron thickness. The fibres were studied by extraction after selective dissolution of the a-AI matrix. There was no interfacial reaction between a-AI and Ti or any measurable oxide formation, thus providing encouragement for the manufacture of metal-metal composites by eo-spray forming. A powder injection pump was successfully integrated and commissioned on the spray forming facility at Oxford University. The pump was calibrated to optimise powder flow rates. Three AI-4Cu+ Ti composite billets were processed with each containing Ti powder with a different processing history. Up to 20vol%Ti was successfully incorporated, however due to the cooling effect from powder injection, porosity was significant. The quenching effect provided a finer AI-4Cu grain structure in the region of Ti injection, and also promoted precipitation of O'-AbCu precipitates. A Ti/ Al-4Cu interfacial reaction was more prominent in the billet spray formed at 850°C than those spray formed at 750°C. Angular Ti processed by a hydride-dehydride route had better deformation characteristics than spherical gas atomised Ti. Deformation processing by extrusion and rolling was investigated for Al-4Cu+20vol%Ti using SEM, EBSD and FIB. After extrusion to a strain of 5, the composite contained elongated reinforcing fibres characteristic of metal-metal composites. The microstructure studied by EBSD revealed equiaxed polygonal Al-4Cu matrix grains. Rolling was not as efficient as extrusion in producing elongated Ti fibres and was attributed to a lower deformation processing temperature. The rolled composites consisted of elongated Al-4Cu grains 1-5J1m in thickness. An UTS of 339MPa at a strain of 3 was attributed to texture strengthening in the Q- AI.
| Identifer | oai:union.ndltd.org:bl.uk/oai:ethos.bl.uk:559831 |
| Date | January 2011 |
| Creators | Kelly, Aoife |
| Contributors | Grant, Patrick |
| Publisher | University of Oxford |
| Source Sets | Ethos UK |
| Detected Language | English |
| Type | Electronic Thesis or Dissertation |
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