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Zr(IV) and Hf(IV) based metal–organic frameworks with reo-topology

Zr and Hf based MOFs with enhanced pore accessibility for large molecules and good hydrothermal stability were obtained using a bent dithienothiophene dicarboxylate and Zr4+ or Hf4+ source. A modulator (benzoic acid) facilitates formation of an eight-connecting cluster leading to a new framework which adopts reo topology. / Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich.

Identiferoai:union.ndltd.org:DRESDEN/oai:qucosa:de:qucosa:27790
Date January 2012
CreatorsBon, Volodymyr, Senkovskyy, Volodymyr, Senkovska, Irena, Kaskel, Stefan
PublisherRoyal Society of Chemistry
Source SetsHochschulschriftenserver (HSSS) der SLUB Dresden
LanguageEnglish
Detected LanguageEnglish
Typedoc-type:article, info:eu-repo/semantics/article, doc-type:Text
SourceChemical communications 2012;48:8407-8409, ISSN: 1359-7345
Rightsinfo:eu-repo/semantics/openAccess
Relation10.1039/c2cc34246d

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