The reaction of Mg(NPh2)2 with LiNR2 (R= SiMe3, NiPr, NiBu) generated the same product, [Mg(NPh2)3(THF)][Li(THF)4] which was identified by 1H-NMR and X-ray crystallography. The magnesium-lithium mixed metal complex reacted with excess carbon dioxide in the ice bath to generate the tetralithium complex, Li4(O2CNPh2)4(THF)4 which was identified by 1H-NMR, 13C-NMR, IR, and X-ray crystallography.
| Identifer | oai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0818103-142841 |
| Date | 18 August 2003 |
| Creators | Chen, Shin-Yi |
| Contributors | Chung-Cheng Chang, none, none, none |
| Publisher | NSYSU |
| Source Sets | NSYSU Electronic Thesis and Dissertation Archive |
| Language | English |
| Detected Language | English |
| Type | text |
| Format | application/pdf |
| Source | http://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0818103-142841 |
| Rights | unrestricted, Copyright information available at source archive |
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