Wang, Minji. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2009. / Includes bibliographical references (leaves 91-97). / Abstracts in English and Chinese. / Acknowledgement --- p.i / Abstract --- p.ii / 摘要 --- p.iii / Chapter Chapter 1. --- Introduction --- p.1 / Chapter 1.1 --- Weak Intermolecular Interactions --- p.1 / Chapter 1.1.1 --- Van der Waals Interaction --- p.1 / Chapter 1.1.2 --- Hydrogen Bonds --- p.2 / Chapter 1.1.3 --- π…π Interactions --- p.4 / Chapter 1.1.4 --- Lone-Pair…Aromatic Interactions --- p.5 / Chapter 1.1.5 --- Halogen…Halogen Interactions --- p.6 / Chapter 1.2 --- Argentophilic Interaction --- p.7 / Chapter 1.3 --- Silver Acetylenediide and Silver Arylethynide --- p.11 / Chapter 1.3.1 --- "C2@Agn(n = 6, 7, 8, 9, 10)" --- p.11 / Chapter 1.3.2 --- "Ag4eC=C-C=Cz>Ag4 and R-C=C@=)Agn, (n = 4, 5; R = Aryl, t-Bu)" --- p.12 / Chapter 1.4 --- Research Strategy --- p.14 / Chapter Chapter 2. --- "Coordination Networks Constructed with the Supramolecular Synthon System Rx-CsCzAgn (n = 4,5; Rx = halophenyl)" --- p.16 / Chapter 2.1 --- Crystal Structure of AgC=CC6H4l-4 ´Ø 2AgCF3COO (2.1) --- p.17 / Chapter 2.2 --- Crystal Structure of AgC=CC6H4l-4 . 3AgNO3 (2.2) --- p.20 / Chapter 2.3 --- "Crystal Structure of 2AgC=CC6H3Cl2-3,4 . 5AgCF3COO ´Ø 2CH3CN . H20 (2.3)" --- p.25 / Chapter 2.4 --- Crystal Structure of 4AgC=CC6H4Cl-3 . 6AgC2F5COO ´Ø 5CH3CN (2.4) & 4AgOCC6H4Br-3 ´Ø 6AgC2F5COO ´Ø 5CH3CN (2.5) --- p.28 / Chapter 2.5 --- Crystal Structure of 2AgC=CC6H4Cl-2 . 4AgCF3COO ´Ø NC(CH2)4CN (2.6) & 2AgOCC6H4Cl-2 ´Ø 4AgCF3COO ´Ø 2CH3CN (2.7) --- p.32 / Chapter 2.6 --- Crystal Structure of AgC=CC6H4F-2 ´Ø 2CF2(CF2COOAg)2 ´Ø 2CH3CN (2.8) --- p.36 / Chapter 2.7 --- Crystal Structure of 4AgC=CC6H4N02-2 ´Ø 10AgC3F7COO ´Ø 4CH3CN . 4H20 (2.9) --- p.39 / Chapter 2.8 --- Summary --- p.41 / Chapter Chapter 3. --- Network Assembly with the Supramolecular Synthon System Rx-C=C3Agw (/i = 3 to 5; Rx = nitrophenyl) --- p.43 / Chapter 3.1 --- Crystal Structure of AgC=CC6H4N02-2 ´Ø 3AgC2F5COO . 2CH3CN (3.1) --- p.44 / Chapter 3.2 --- Crystal Structure of AgC=CC6H4N02-4 ´Ø 3AgC2F5COO ´Ø CH3CN (3.2) --- p.47 / Chapter 3.3 --- Crystal Structure of AgC=CC6H4N02-4 ´Ø 4AgCF3COO ´Ø 2CH3CN (3.3) --- p.50 / Chapter 3.4 --- Crystal Structure of AgC=CC6H4N02-4 ´Ø 3AgCF3COO . CH3CN ´Ø 0.5NC(CH2)4CN (3.4) --- p.53 / Chapter 3.5 --- Crystal Structure of AgC=CC6H4N02-4 ´Ø 3AgC2F5COO ´Ø 2CH3CN (3.5) --- p.56 / Chapter 3.6 --- Crystal Structure of AgC=CC6H4N02-4 ´Ø 3AgC2F5COO ´Ø CH3CN ´Ø NC(CH2)4CN (3.6) --- p.59 / Chapter 3.7 --- Crystal Structure of 4AgC三CC6H4NOr4 ´Ø 4AgC3F7COO ´Ø 3CH3CN (3.7) --- p.62 / Chapter 3.8 --- Crystal Structure of 3AgC=CC6H4N02-4 ´Ø 3AgCF3COO ´Ø 3CH3CN (3.8) --- p.66 / Chapter 3.9 --- Crystal Structure of 7AgC三CC6H4NOr4 ´Ø 17AgCF3COO ´Ø 11CH3CN ´Ø H20 (3.9) --- p.68 / Chapter 3.10 --- Crystal Structure of AgC=CC6H4N02-4 ´Ø CF2(CF2COOAg)2. AgCFsCOO . H2O (3.10) --- p.72 / Chapter 3.11 --- Summary --- p.76 / Chapter 3.12 --- Further Development --- p.77 / Chapter 3.12.1 --- Elongation of Ethynide Ligands --- p.77 / Chapter 3.12.2 --- Incorporating More Ethynide Ligands into One Compound --- p.78 / Chapter Chapter 4. --- Experimental --- p.79 / Chapter 4.1 --- Synthesis --- p.79 / Chapter 4.2 --- X-Ray Crystallography --- p.84 / References --- p.91
| Identifer | oai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_326538 |
| Date | January 2009 |
| Contributors | Wang, Minji., Chinese University of Hong Kong Graduate School. Division of Chemistry. |
| Source Sets | The Chinese University of Hong Kong |
| Language | English, Chinese |
| Detected Language | English |
| Type | Text, bibliography |
| Format | print, v, 97 leaves : ill. ; 30 cm. |
| Rights | Use of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/) |
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