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Synthesis of novel sterically constrained aryl-alkyne type molecules for nonlinear optical studies / by Timothy Paul Bubner.

Bibliography: leaves 220-230. / iv, 230, [25] leaves : ill. ; 30 cm. / Title page, contents and abstract only. The complete thesis in print form is available from the University Library. / This thesis performs a modeling study on a number of sterically constrained aryl-alkyne type systems with the results being used to guide subsequent synthetic efforts. Disulfide, silylene, stannyl, oxalate and 1,2-dioxaethyl and 1,3-dioxapropyl linkages are investigated as candidates to constrain the rotation of the tolane substructure. A preliminary Z-scan experiment is developed and is demonstrated as being able to detect optical nonliniarities. / Thesis (Ph.D.)--University of Adelaide, Dept. of Chemistry, 1997?

Identiferoai:union.ndltd.org:ADTP/260224
Date January 1996
CreatorsBubner, Timothy Paul
Source SetsAustraliasian Digital Theses Program
Languageen_US
Detected LanguageEnglish

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