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Syntheses of Highly Strained Energetic Molecules and Development of New Synthetic Methodology

The objective of this study was to synthesize new energetic, strained, saturated polycyclic compounds. For this purpose, new methodology has been developed, as follows: (i) Ketenes have been generated in situ via treatment of aldo-, keto- or alkenoic acid with either toluenesulfonyl chloride or 2-chloro-1-methylpyridfniurn iodide (Mulkaiyama's reagent). The reactive intermediates thereby generated have been found to undergo intramolecular [2+2] cycloaddition reactions in these systems.

Identiferoai:union.ndltd.org:unt.edu/info:ark/67531/metadc331132
Date05 1900
CreatorsWu, An-hsiang
ContributorsMarchand, Alan P., Schwartz, Martin, Theriot, L. J., Jones, Paul R., Brady, William Thomas
PublisherNorth Texas State University
Source SetsUniversity of North Texas
LanguageEnglish
Detected LanguageEnglish
TypeThesis or Dissertation
Formatv, 139 leaves: ill., Text
RightsPublic, Wu, An-hsiang, Copyright, Copyright is held by the author, unless otherwise noted. All rights reserved.

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