The Electronic transition ²Σ-X²Π of N₂0⁺ has been observed at high resolution and a more thorough analysis of the spectrum has been undertaken than was previously available in the literature.
Twenty-four bands of the spectrum have been fitted into a vibrational energy level scheme. Of these, eighteen were found to involve only the vibrations Ʋ₁ and Ʋ₃. The remainder of the bands were ascribed to the vibration Ʋ₂, and were found to be explainable in terms of Renner effects coupling the transverse vibration and the orbital angular momentum of the ²π Electronic state.
Rotational analyses of varying degrees of thoroughness have been made of seven bands. Various molecular constants have been deduced, including α₁, α₃, p ( the Λ - doubling constant), and q ( the 1-doubling constant of the upper state vibrational level 010). / Science, Faculty of / Physics and Astronomy, Department of / Graduate
| Identifer | oai:union.ndltd.org:UBC/oai:circle.library.ubc.ca:2429/38356 |
| Date | January 1964 |
| Creators | Abernethy, Emerson Randle |
| Publisher | University of British Columbia |
| Source Sets | University of British Columbia |
| Language | English |
| Detected Language | English |
| Type | Text, Thesis/Dissertation |
| Rights | For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use. |
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