Arsonoacetic acid, H₂O₃As¹CH₂COOH, and arsenoacetic acid, punitively [AsVCH₂COOH]₂ have been synthesised according to historical literature methods, and have been characterised using modern techniques. Arsonoacetic acid was shown by an X-ray crystal structure analysis to be a molecular species with an extensive hydrogen bonding network in the crystal. Arsenoacetic acid proved to be more enigmatic. Electrospray mass spectra suggested it consisted of a mixtures of rings (RAs)n, n = 3-11, with n = 6 dominating. This was partly confirmed by a crystal structure of (AsCH₂COOH)₆ (as the pyridine solvate). On the other hand, ¹H and ¹³C NMR gave spectra that indicated only a single component for arsenoacetic acid. The formation of crystals of the high temperature phase of elemental sulfur, β-S8, at ambient temperature is also discussed.
| Identifer | oai:union.ndltd.org:ADTP/242625 |
| Date | January 2009 |
| Creators | Wilson, Peter Stanley |
| Publisher | The University of Waikato |
| Source Sets | Australiasian Digital Theses Program |
| Language | English |
| Detected Language | English |
| Rights | http://www.waikato.ac.nz/copyright.shtml |
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