Return to search

The Kinetics and Mechanism of the Reaction of Molybdenum(V) with Iodine, Oxygen and Nitrate

Molybdenum compounds present a series of baffling chemical puzzles. By no means are all of these yet even clearly defined and many may never be. This complexity results from the ability of molybdenum to form six different oxidation states, which can possess three different coordination numbers. Furthermore, molybdenum compounds readily disproportionate to yield mixed valence compounds; and finally, molybdate ions readily aggregate in solution to form a variety of polyions by polymerization-condensation reactions which are controlled by pH and the concentration of the system. Molybdenum' s complexity can best be summed up in the words of the late Edgar Smith who described molybdenum to his classes as “ambidextrous, bi-sexual and polygamous.”

Identiferoai:union.ndltd.org:UTAHS/oai:digitalcommons.usu.edu:etd-8360
Date01 May 1965
CreatorsGuymon, Ervin Park
PublisherDigitalCommons@USU
Source SetsUtah State University
Detected LanguageEnglish
Typetext
Formatapplication/pdf
SourceAll Graduate Theses and Dissertations
RightsCopyright for this work is held by the author. Transmission or reproduction of materials protected by copyright beyond that allowed by fair use requires the written permission of the copyright owners. Works not in the public domain cannot be commercially exploited without permission of the copyright owner. Responsibility for any use rests exclusively with the user. For more information contact digitalcommons@usu.edu.

Page generated in 0.002 seconds