3-Cyanopropyl(diphenyl)phosphine was synthesized from chloro(diphenyl)phosphine and 4-chlorobutyronitrile. This new ligand, along with (C6H5)2PCH2CN and (C6H5)2PCH2CH(CH3)CN were reacted with Re(CO)5X (X=Cl,Br) in 1:1 and 1:2.5 (metal:ligand) mole ratios.For all ligands, complexes with the stoichiometry Re(CO)3L2X were isolated from the 1:2.5 mole ratio reactions. Spectroscopic data suggest that the CO groups are facial and the ligands cis to each other.For all ligands, complexes with the stoichiometry Re2(CO)6L2X2 were isolated from the 1:1 mole ratio reactions. Spectroscopic evidence suggests that all the complexes are ligand bridged dimers which utilize the phosphorus and nitrogen lone pairs of the ligand.Ball State UniversityMuncie, IN 47306
| Identifer | oai:union.ndltd.org:BSU/oai:cardinalscholar.bsu.edu:handle/181810 |
| Date | 03 June 2011 |
| Creators | Worstell, Jonathan Harlan |
| Contributors | Storhoff, Bruce N. |
| Source Sets | Ball State University |
| Detected Language | English |
| Format | iii, 39 leaves ; 28 cm. |
| Source | Virtual Press |
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