The SPECIFIC method a fast and accurate method for generating shaped femtosecond laser pulses. The femtosecond pulses are user specified from pulse parameters in the temporal domain. The measured spectral and recovered temporal phase and amplitudes from SEA TADPOLE are compared with the theoretical pulse profile from the user specified input. The SPECIFIC method has been shown to be a technique that can generate a diverse array of spectral/temporal phase and amplitude as well as polarization pulse shapes for numerous scientific applications. The spatio -temporal -spectral properties of focusing femtosecond laser pulses are studied for several pulse shapes that are important for non-linear spectroscopic studies. We have shown with scanning SEA TADPOLE that the spatio-spectral phase of focusing double pulse profile changes across the laterally across the beam profile. The spectral features of the sinusoidal spectral phase shaped pulse has been shown to tilt at with a changing angle away from the focus of the lens. Using spatio-spectral coupling, we have shown that multiple spatio-temporal foci can be generated along and perpendicular to the focusing direction of a femtosecond laser pulse. The spatial position of the spatio-temporal foci is controlled optically. Using sinusoidal spectral phase modulated pulse trains fragment ion production from Benzonitrile parent molecule can be controlled. A spectral transmission window perturbed the temporal pulse amplitudes resulting in fragment ion production dependant on spectral window position. The spectral window ion production was shown to also be dependant on temporal phase sequence. / Chemistry
| Identifer | oai:union.ndltd.org:TEMPLE/oai:scholarshare.temple.edu:20.500.12613/1013 |
| Date | January 2012 |
| Creators | Coughlan, Matthew Anthony |
| Contributors | Levis, Robert J., Matsika, Spiridoula, Borguet, Eric, Lyyra, A. Marjatta |
| Publisher | Temple University. Libraries |
| Source Sets | Temple University |
| Language | English |
| Detected Language | English |
| Type | Thesis/Dissertation, Text |
| Format | 253 pages |
| Rights | IN COPYRIGHT- This Rights Statement can be used for an Item that is in copyright. Using this statement implies that the organization making this Item available has determined that the Item is in copyright and either is the rights-holder, has obtained permission from the rights-holder(s) to make their Work(s) available, or makes the Item available under an exception or limitation to copyright (including Fair Use) that entitles it to make the Item available., http://rightsstatements.org/vocab/InC/1.0/ |
| Relation | http://dx.doi.org/10.34944/dspace/995, Theses and Dissertations |
Page generated in 0.0025 seconds