Thesis advisor: Jeremy Shakun / Thesis advisor: Tony Wang / To better understand ice sheet and nutrient cycling dynamics in the North Atlantic, three geochemical paleo-proxies have been analyzed in Pleistocene marine sediments: cosmogenic nuclides (10Be and 26Al) in ice-rafted debris (IRD), 40Ar/39Ar in IRD, and foraminifera-bound nitrogen isotopes (FB-δ15N). For Chapter 1, we analyzed 10Be and 26Al concentrations in quartz separates of IRD from last-glacial North Atlantic sediments and used these data to constrain the history of Laurentide Ice Sheet (LIS) cover over Canada during the Pleistocene. While LIS history is well constrained since the Last Glacial Maximum (LGM) (~20,000 years ago), there is little evidence available from earlier times. 26Al/10Be ratios are depressed in these samples, the result of long-term decay under cover, which we suggest is best explained by a persistent LIS over much of the last million years. This finding implies that the LIS did not fully disappear during many Pleistocene interglacials, making the current ice-free Holocene interglacial relatively unique.
For Chapter 2, we synthesized 3,762 40Ar/39Ar ages from North Atlantic IRD, including 670 new analyses. 595 of these single-grain analyses come from some of the same sample intervals as Chapter 1. These 40Ar/39Ar ages in IRD, a tracer of IRD provenance, clarify changes in North Atlantic ice sheet extent during the past few glacial cycles. Comparison of 40Ar/39Ar ages with hypothesized ice margins and cosmogenic nuclide data (from Chapter 1) aid in our interpretations. For last-glacial samples, results suggest ice sheets around the basin may have been in a retracted state during Marine Isotope Stage (MIS) 3 (~29-57 ka), an interval of debated ice extent for the LIS. Our synthesis also allows us to present the first complete records 40Ar/39Ar ages in IRD during Heinrich intervals – times when the LIS exhibited iceberg discharge events. These results support the suggestion made by previous work that Heinrich events 3 and 6 are anomalous relative to other intervals. 40Ar/39Ar analyses from earlier glacial periods – the first yet published – highlight that IRD provenance data may be reflecting iceberg survivability in addition to changes in ice extent. Lastly, analyzing cosmogenic nuclides and 40Ar/39Ar ages in IRD from the same sample intervals indicates that both proxies may be used to infer changes in ice sheet provenance; this is the first time cosmogenic nuclides in IRD have been considered in this way.
For Chapter 3, we analyzed FB-δ15N at Site U1313 in North Atlantic samples during the Plio-Pleistocene to reconstruct marine nutrient cycling. In the North Atlantic, nutrient cycling is known to play an important role in regulating surface ocean productivity and CO2 drawdown via photosynthesis. We nevertheless lack a complete understanding of nutrient cycling evolution for the Plio-Pleistocene, during which Northern Hemisphere ice sheets and climate exhibited dramatic fluctuations. We find increasing FB-δ15N values at the transition from the Pliocene to the Pleistocene. Additionally, FB-δ15N values are generally higher during glacials compared to interglacials. We suggest these observations can best be explained by an expansion or increase of N2 fixation in the North Atlantic during warmer intervals (interglacials, Pliocene) and a retraction or decrease of N2 fixation during cold intervals (Pleistocene glacials). Considered alongside previously published paleo-proxy data from Site U1313 we suggest these changes in nutrient cycling reflect climate-driven migrations of the North Atlantic Current.
In Chapter 4, I reflect upon how I have worked to integrate broader impacts into my Ph.D. work. Using a combined approach, I focused on fostering an inclusive environment within paleoclimate research spaces as well as engaging non-scientists in paleoclimate-and Earth science-related activities. These approaches ranged from K-12 partnership activities to mentoring students to more experimental avenues, such as a collaborative art project. I have evaluated the success of this work using a combination of quantitative metrics and subjective assessments. Participating in these efforts was also crucial for reminding me of the importance of making science accessible to everyone as well as for helping me hone my mentorship and science communication skills. / Thesis (PhD) — Boston College, 2024. / Submitted to: Boston College. Graduate School of Arts and Sciences. / Discipline: Earth and Environmental Sciences.
| Identifer | oai:union.ndltd.org:BOSTON/oai:dlib.bc.edu:bc-ir_110039 |
| Date | January 2024 |
| Creators | LeBlanc, Danielle E. |
| Publisher | Boston College |
| Source Sets | Boston College |
| Language | English |
| Detected Language | English |
| Type | Text, thesis |
| Format | electronic, application/pdf |
| Rights | Copyright is held by the author, with all rights reserved, unless otherwise noted. |
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