Elevated toxaphene levels have been reported in the biota of the Arctic. The purpose of this study is to measure total toxaphene levels in food samples commonly consumed by the Canadian Inuit and study the relationship between concentrations of total toxaphene and individual congeners. A total of 127 Inuit food samples were collected for toxaphene analysis. Total toxaphene and the specific toxaphene congeners including Parlar #26, #40/41, #42, #44, #50 and #62 were detected in the food samples. Total toxaphene concentrations ranged from 13 to 2800 ng/g and various congener concentrations ranged from 0 to 610 ng/g. Concentrations of total toxaphene were strongly correlated with congener concentration in marine mammals and weaker in fish. The sum of congeners Parlar #26, #50 and #62 accounted for 0--15% of total toxaphene in fish and 0--66% in marine mammals. Regression models were used to estimate total toxaphene based on individual or combinations of congener concentrations. Dietary intake was estimated to be 1.07 and 0.78 mug/kg body weight per day in Chesterfield Inlet and Igloolik. Our results show that there is no general conversion factor that can be used to estimate total toxaphene concentrations based on congener measurements.
Identifer | oai:union.ndltd.org:LACETR/oai:collectionscanada.gc.ca:QMM.33732 |
Date | January 2001 |
Creators | Chu, Fong Lam, 1976- |
Contributors | Chan, H. M. (advisor) |
Publisher | McGill University |
Source Sets | Library and Archives Canada ETDs Repository / Centre d'archives des thèses électroniques de Bibliothèque et Archives Canada |
Language | English |
Detected Language | English |
Type | Electronic Thesis or Dissertation |
Format | application/pdf |
Coverage | Master of Science (School of Dietetics and Human Nutrition.) |
Rights | All items in eScholarship@McGill are protected by copyright with all rights reserved unless otherwise indicated. |
Relation | alephsysno: 001872282, proquestno: MQ78849, Theses scanned by UMI/ProQuest. |
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