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The Oxygen Fugacity Relationships At The Contact of The E-F Horizons of The Eastern Bushveld

A review of the theory and evolution of fO2 cells is given. Particular attention is paid to the double cell design of Sato (1971). The incorporation of a servo mechanism after Sato (1971) is discussed. Calibration procedures for the entire system are presented with some emphasis on the use of nickel-neckel oxide and synthetic magnetite. The petrology of the Bushveld is reviewed in light of a possible fO2 hypothesis for the Critical Zone. Results of an examination of the E-F contact, Critical Zone, Eastern Bushveld, show a last equilibration at 1075 C and at a log10 fO2 value of -12.20. Two explanations are suggested for this intersection point: 1. It is the solidus, fO2 and temperature of the Bushveld magma at this horizon. 2. It is the post-cumulus, i.e., sub-solidus, fO2 and temperature of equilibration for the Bushveld rocks at the F-horizon. The first explanation is favored by the author and is being pursued currently. The second explanation requires ferrous/ferric equilibration but not chemical equilibration. This phenomenon is discussed from the consideration of diffusion rates for various ions. / Earth and Environmental Science

Identiferoai:union.ndltd.org:TEMPLE/oai:scholarshare.temple.edu:20.500.12613/8422
Date January 1972
CreatorsFlynn, Ronald T.
ContributorsUlmer, Gene Carleton, 1937-2015, Myer, George H., Tappe, John
PublisherTemple University. Libraries
Source SetsTemple University
LanguageEnglish
Detected LanguageEnglish
TypeThesis/Dissertation, Image
Format106 pages
RightsIN COPYRIGHT- This Rights Statement can be used for an Item that is in copyright. Using this statement implies that the organization making this Item available has determined that the Item is in copyright and either is the rights-holder, has obtained permission from the rights-holder(s) to make their Work(s) available, or makes the Item available under an exception or limitation to copyright (including Fair Use) that entitles it to make the Item available., http://rightsstatements.org/vocab/InC/1.0/
Relationhttp://dx.doi.org/10.34944/dspace/8386, Digital copy of print original., Theses and Dissertations

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