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Synthesis and properties of optically active, axially chiral oligomers.

by Man-Kit Ng. / Thesis (M.Phil.)--Chinese University of Hong Kong, 1996. / Includes bibliographical references (leaves 60-69). / Contents --- p.i / Acknowledgments --- p.ii / Publications --- p.iii / Abstract --- p.iv / Abbreviations --- p.v / Chapter 1. --- Introduction / Chapter 1.1 --- General Background of Optically Active Polymers and Oligomers --- p.1 / Chapter 1.2 --- Optically Active Conjugated Polymers with Main Chain Chirality --- p.6 / Chapter 1.3 --- Optically Active Oligomers with Main Chain Chirality --- p.8 / Chapter 2. --- Design of Optically Active Oligomers with Main Chain Chirality / Chapter 2.1 --- Structure of the Oligomers --- p.11 / Chapter 2.2 --- Selection of Chiral Element --- p.11 / Chapter 2.3 --- Selection of Spacer Linkage --- p.13 / Chapter 3. --- Synthetic Routes to Optically Pure l,l'-Bi-2-naphthols / Chapter 3.1 --- Asymmetric Synthesis --- p.16 / Chapter 3.2 --- "Synthesis and Optical Resolution of l,l'-Bi-2-naphthols" --- p.19 / Chapter 4. --- Synthesis and Characterization of Optically Active Binaphthol-based Oligomers / Chapter 4.1 --- Synthesis of Enantiomerically Pure Monomer41 --- p.23 / Chapter 4.2 --- Oligomerization of the Monomer41 --- p.33 / Chapter 4.3 --- Characterization of Binaphthol-based Oligomers 41 -44 --- p.35 / Chapter 5. --- Properties of Optically Active Oligomers 41 - --- p.44 / Chapter 5.1 --- Physical Appearance and Solubility Property --- p.40 / Chapter 5.2 --- Ultraviolet Spectroscopy --- p.40 / Chapter 5.3 --- Polarimetry Studies --- p.42 / Chapter 5.4 --- Circular Dichroism Studies --- p.43 / Chapter 5.5 --- Cyclic Voltammetric Studies --- p.45 / Chapter 6. --- Conclusions --- p.48 / Chapter 7. --- Experimental --- p.49 / References --- p.60 / Spectra --- p.70

Identiferoai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_321542
Date January 1996
ContributorsNg, Man-Kit., Chinese University of Hong Kong Graduate School. Division of Chemistry.
PublisherChinese University of Hong Kong
Source SetsThe Chinese University of Hong Kong
LanguageEnglish
Detected LanguageEnglish
TypeText, bibliography
Formatprint, v, 89 leaves : ill. ; 30 cm.
RightsUse of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/)

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