Kwok, Wun Sang. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2007. / Includes bibliographical references (leaves 147-152). / Abstracts in English and Chinese. / Acknowledgment --- p.i / Table of Contents --- p.ii / Abstract --- p.iii / Abstract (Chinese Version) --- p.iv / Abbreviation --- p.v / Chapter 1. --- Introduction --- p.1 / Chapter 1.1 --- General Background --- p.1 / Chapter 1.1.1 --- "1,3-Dipolar Cycloaddition" --- p.1 / Chapter 1.1.2 --- Structure of Preparation of Nitrile Oxide --- p.3 / Chapter 1.2 --- Intramolecular Nitrile Oxide Alkene Cyclization (INOC) --- p.7 / Chapter 1.2.1 --- INOC in Organic Synthesis --- p.7 / Chapter 1.2.2 --- Formation of Oximolactone as Unwanted Reaction in INOC --- p.10 / Chapter 1.2.3 --- Nitrile Oxide Alkene Cyclization with Free Hydroxyl Group --- p.11 / Chapter 1.3 --- Natural Occurring Gabosine --- p.14 / Chapter 1.3.1 --- "Structure, Biological Effect and Syntheses of Gabosines" --- p.14 / Chapter 1.3.2 --- Synthesis of Gabosine O and its 4-epimer --- p.17 / Chapter 1.4 --- Protected 6-dehydroxy-Pseudo-a-D-Talose --- p.21 / Chapter 1.4.1 --- Structures and Biological Effects of Valienamine and its Derivatives --- p.21 / Chapter 1.4.2 --- Structural and Biological Studies of Valienamine by Our Group --- p.23 / Chapter 2. --- Results and Discussion --- p.28 / Chapter 2.1 --- Studies on INOC of Sugar Derivatives with Free Hydroxyl Group(s) --- p.28 / Chapter 2.2 --- Enantiospecific Synthesis of 4-epi-Gabosine O --- p.47 / Chapter 2.3 --- Enantiospecific Synthesis of Gabosine O --- p.84 / Chapter 2.4 --- Synthesis of 6-Deoxy-Pseudo-a-D-Talose --- p.87 / Chapter 3. --- Conclusion --- p.95 / Chapter 4. --- Experimental --- p.100 / References --- p.147 / Appendix NMR spectra --- p.153
Identifer | oai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_326182 |
Date | January 2007 |
Contributors | Kwok, Wun Sang., Chinese University of Hong Kong Graduate School. Division of Chemistry. |
Source Sets | The Chinese University of Hong Kong |
Language | English, Chinese |
Detected Language | English |
Type | Text, bibliography |
Format | print, vi, 152 leaves : ill. ; 30 cm. |
Rights | Use of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/) |
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