The main focus of this thesis is to present the structural and photophysical characteristics of the coordination polymers [Ln(C7H3NO4)(C7H4NO4)(H2O)]n (Ln is Pr, Nd, Sm, Eu, and Tb), as well as attempting to synthesize the novel organic linker 4,4'(4,8-Dihydrobenzo[1,2-b:4,5-b']dithiophene-4,8-diyl)dibenzoic acid (BDTDC). Various lanthanide salts were coordinated with 2,3-pyridinecarboxylate (2,3- pydc) via hydrothermal synthesis. ... Progress was made toward the synthesis of a novel metal-organic framework linker BDTDC. Synthesis of the intermediate benzo[1,2-b:4,5-b']dithiophene as well as the determination of the crystal structure, were performed successfully and are reported herein. / by Amanda Lyn Staggeer Ramirez. / Thesis (M.S.)--Florida Atlantic University, 2013. / Includes bibliography. / Mode of access: World Wide Web. / System requirements: Adobe Reader.
Identifer | oai:union.ndltd.org:fau.edu/oai:fau.digital.flvc.org:fau_4209 |
Contributors | Ramirez, Amanda Lyn Staggers., Charles E. Schmidt College of Science, Department of Chemistry and Biochemistry |
Publisher | Florida Atlantic University |
Source Sets | Florida Atlantic University |
Language | English |
Detected Language | English |
Type | Text, Electronic Thesis or Dissertation |
Format | xii, 61 p. : ill. (some col.), electronic |
Rights | http://rightsstatements.org/vocab/InC/1.0/ |
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