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Toward the synthesis of organic moieties for use in luminescent lanthanide materials: from benzodithiophene based linkers to a series of 2,3 pyridinedicarboxylate coordination polymers

The main focus of this thesis is to present the structural and photophysical characteristics of the coordination polymers [Ln(C7H3NO4)(C7H4NO4)(H2O)]n (Ln is Pr, Nd, Sm, Eu, and Tb), as well as attempting to synthesize the novel organic linker 4,4'(4,8-Dihydrobenzo[1,2-b:4,5-b']dithiophene-4,8-diyl)dibenzoic acid (BDTDC). Various lanthanide salts were coordinated with 2,3-pyridinecarboxylate (2,3- pydc) via hydrothermal synthesis. ... Progress was made toward the synthesis of a novel metal-organic framework linker BDTDC. Synthesis of the intermediate benzo[1,2-b:4,5-b']dithiophene as well as the determination of the crystal structure, were performed successfully and are reported herein. / by Amanda Lyn Staggeer Ramirez. / Thesis (M.S.)--Florida Atlantic University, 2013. / Includes bibliography. / Mode of access: World Wide Web. / System requirements: Adobe Reader.

Identiferoai:union.ndltd.org:fau.edu/oai:fau.digital.flvc.org:fau_4209
ContributorsRamirez, Amanda Lyn Staggers., Charles E. Schmidt College of Science, Department of Chemistry and Biochemistry
PublisherFlorida Atlantic University
Source SetsFlorida Atlantic University
LanguageEnglish
Detected LanguageEnglish
TypeText, Electronic Thesis or Dissertation
Formatxii, 61 p. : ill. (some col.), electronic
Rightshttp://rightsstatements.org/vocab/InC/1.0/

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