Peng Yu. / Thesis (M.Phil.)--Chinese University of Hong Kong, 1999. / Includes bibliographical references. / Abstracts in English and Chinese. / Table of Contents --- p.i / Acknowledgements --- p.iv / Abstract --- p.v / Abbreviations --- p.ix / Chapter CHAPTER 1. --- METALLATION OF AMINOPYRIDINE AND AMINOQUINOLINE / Chapter 1.1 --- INTRODUCTION / Chapter 1.1.1 --- General Background --- p.1 / Chapter 1.1.2 --- Synthesis of Metal Amides --- p.2 / Chapter 1.1.3 --- General Review of Lithium Amido Complexes --- p.4 / Chapter 1.1.4 --- Structures of Some Potassium and Sodium Amido Complexes --- p.8 / Chapter 1.1.5 --- A Brief Review of TV-functionalized Amido Metal Complexes --- p.9 / Chapter 1.1.6 --- Objective of This Work --- p.13 / Chapter 1.2 --- RESULTS AND DISCUSSION / Chapter 1.2.1 --- Synthesis of N-functionalized Amido Ligands --- p.14 / Chapter 1.2.2 --- Lithiation of Aminopyridine --- p.15 / Chapter 1.2.3 --- Lithiation of Aminoquinoline --- p.17 / Chapter 1.2.4 --- Attempted Synthesis of Sodium Amido Complexes --- p.19 / Chapter 1.2.5 --- Attempted Synthesis of Potassium Amido Complexes --- p.19 / Chapter 1.2.6 --- Physical Characterizations of and Compounds 1-10 --- p.20 / Chapter 1.2.7 --- "Molecular Structures of Compounds 3，4, 7, 8, and10" --- p.24 / Chapter 1.3 --- EXPERIMENTALS FOR CHAPTER 1 --- p.37 / Chapter 1.4 --- REFERENCES FOR CHAPTER 1 --- p.44 / Chapter CHAPTER 2. --- SYNTHESIS AND STRUCTURES OF GROUP12 AMIDO COMPLEXES / Chapter 2.1 --- INTRODUCTION / Chapter 2.1.1 --- General Review of Zinc(II) Amido Complexes --- p.49 / Chapter 2.1.2 --- General Review of Cadmium(II) Amido Complexes --- p.53 / Chapter 2.1.3 --- General Review of Mercury(II) Amido Complexes --- p.56 / Chapter 2.2 --- RESULTS AND DISCUSSION / Chapter 2.2.1 --- Synthesis of Homoleptic Zinc(II) Amido Complexes --- p.58 / Chapter 2.2.2 --- Attempted Reaction of Compounds [Zn(L1)2] and [Zn(L3)2] (11) with ArSH and S --- p.59 / Chapter 2.2.3 --- Attempted Reaction of [Zn(L1)Cl] with ArSLi and ArMe OLi --- p.59 / Chapter 2.2.4 --- Synthesis of Cadmium(II) Amido Complexes --- p.61 / Chapter 2.2.5 --- "Attempted Reaction of [{Cd(L3)2}2(tmeda)] (16) with S， Se, and ArSH" --- p.63 / Chapter 2.2.6 --- "Attempted Reaction of [Cd(L3)2] (15) with 4,4'- bipyridine" --- p.64 / Chapter 2.2.7 --- Synthesis of Mercury(II) Amido Complexes --- p.65 / Chapter 2.2.8 --- "Reaction of [Hg(L3)2] (21) with S, Se, and ArSH " --- p.67 / Chapter 2.2.9 --- Physical Characterizations of Compounds 11-23 --- p.68 / Chapter 2.2.10 --- "Molecular Structures of Compounds 11, 13, 16, and 21" --- p.73 / Chapter 2.3 --- EXPERIMENTALS FOR CHAPTER 2 --- p.84 / Chapter 2.4 --- REFERENCES FOR CHAPTER 2 --- p.94 / Chapter CHAPTER 3. --- SYNTHESIS AND STRUCTURES OF COPPER AND SILVER(I) AMIDO COMPLEXES / Chapter 3.1 --- INTRODUCTION / Chapter 3.1.1 --- Overview of Transition Metal Amides --- p.99 / Chapter 3.1.2 --- General Review of Copper Amido Complexes --- p.101 / Chapter 3.1.3 --- General Review of Silver(I) Amido Complexes and their Derivatives --- p.105 / Chapter 3.2 --- RESULTS AND DISCUSSION / Chapter 3.2.1 --- Synthesis of Homoleptic Copper(I) Amido Complexes --- p.108 / Chapter 3.2.2 --- Reaction of [{Cu(L3)}2] (24) with ArSH and Dioxygen --- p.110 / Chapter 3.2.3 --- Synthesis of Homoleptic Copper(II) Amido Complexes --- p.111 / Chapter 3.2.4 --- Attempted Reaction of CuCl2 with [{Li(L4)}3] (8) --- p.112 / Chapter 3.2.5 --- Attempted Reaction of [Cu(L3)2] (24) with ArSH --- p.112 / Chapter 3.2.6 --- Synthesis of Silver(I) Amido Complexes --- p.113 / Chapter 3.2.7 --- Attempted Reaction of AgN03 with [{Li(L4)}3] (8) --- p.114 / Chapter 3.2.8 --- Physical Characterizations of Compounds 24-29 --- p.115 / Chapter 3.2.9 --- "Molecular Structures of Compounds 24, 25, 26, and28" --- p.119 / Chapter 3.3 --- EXPERIMENTALS FOR CHAPTER 3 --- p.131 / Chapter 3.4 --- REFERENCES FOR CHAPTER 3 --- p.138 / Chapter CHAPTER 4. --- SYNTHESIS AND STRUCTURES OF NICKEL(II) AMIDO COMPLEXES / Chapter 4.1 --- INTRODUCTION / Chapter 4.1.1 --- General Review of Nickel Derivatives --- p.139 / Chapter 4.2 --- RESULTS AND DISCUSSION / Chapter 4.2.1 --- Synthesis of Homoleptic Nickel(II) Amido Complexes --- p.144 / Chapter 4.2.2 --- Attempted Reaction of NiCl2 with [Li(L3)(tmeda)] (3) --- p.145 / Chapter 4.2.3 --- Physical Characterizations of Compounds 30-32 --- p.145 / Chapter 4.2.4 --- Molecular Structures of Compounds 31 and 32 --- p.147 / Chapter 4.3 --- EXPERIMENTALS FOR CHAPTER 4 --- p.153 / Chapter 4.4 --- REFERENCES FOR CHAPTER 4 --- p.155 / Chapter APPENDIX 1 --- General Procedures and Physical Measurements --- p.157 / Chapter APPENDIX 2 --- "Table A-1. Selected Crystallographic Data for Compounds 3, 4, 7, and 8" --- p.160 / "Table A-2. Selected Crystallographic Data for Compounds 10, 11, 13，and 16" --- p.161 / "Table A-3. Selected Crystallographic Data for Compounds 21, 24, 25, and 26" --- p.162 / "Table A-4. Selected Crystallographic Data for Compounds 28，31, and 32" --- p.163
| Identifer | oai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_322841 |
| Date | January 1999 |
| Contributors | Peng, Yu., Chinese University of Hong Kong Graduate School. Division of Chemistry. |
| Source Sets | The Chinese University of Hong Kong |
| Language | English, Chinese |
| Detected Language | English |
| Type | Text, bibliography |
| Format | print, ix, 163 leaves : ill. ; 30 cm. |
| Rights | Use of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/) |
Page generated in 0.0019 seconds