by Chun Wing Lai. / Thesis submitted in: August 2002. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2003. / Includes bibliographical references (leaves 87-92). / Abstracts in English and Chinese. / ACKNOWLEDMENTS --- p.1 / CONTENTS --- p.2 / ABTRACT --- p.5 / Chapter CHAPTER 1 --- INTRODUCTION --- p.7 / Chapter 1.1 --- General background --- p.7 / Chapter 1.2 --- Synthesis of tetraphenylene and its derivatives --- p.8 / Chapter 1.2.1 --- From electrophililc aromatic substitution --- p.9 / Chapter 1.2.2 --- From biphenylene pyrolysis --- p.10 / Chapter 1.2.3 --- From aryl halide coupling --- p.13 / Chapter 1.2.4 --- From bis-acetylene --- p.15 / Chapter 1.2.5 --- Synthesis of tetraphenylenes fused with carbocycles and heterocycles --- p.17 / Chapter 1.3 --- Inversion barrier of tetraphenylenes --- p.21 / Chapter 1.4 --- Clathrate inclusion properties of tetraphenylene and its derivatives --- p.27 / Chapter 1.5 --- Tetraphenylenols --- p.33 / Chapter CHAPTER 2 --- RESULTS AND DISCUSSION / Chapter 2.1 --- Aim of the present work --- p.38 / Chapter 2.2 --- "Retrosynthetic studies on 1,4,5,8,9,12,13,16-octahydroxytetraphenylene" --- p.39 / Chapter 2.2.1 --- "1,4,5,8-tetramethoxybiphenylene approach" --- p.39 / Chapter 2.2.2 --- "2,2'-diiodo-3,3',6,6'-tetramethoxybiphenyl approach" --- p.42 / Chapter 2.3 --- "Preparation of 1,4,5,8-tetramethoxybiphenylene" --- p.44 / Chapter 2.3.1 --- "From 2-amino-3,6-dimethoxybenzoic acid" --- p.44 / Chapter 2.3.2 --- "From l-amino-4,7-dimethoxybenzotriazole" --- p.47 / Chapter 2.4 --- "Synthesis of 1,4,5,8,9,12,13,16-octamethoxytetraphenylene from 1,4,5,8-tetramethoxybiphenylene" --- p.50 / Chapter 2.5 --- "Synthesis of 2,2'-diiodo-3,3',6,6'-tetramethoxybiphenyl" --- p.51 / Chapter 2.6. --- "Synthesis of 1,4,5,8,9,12,13,16-octamethoxytetraphenylene from 2,2，-diiodo-3,3 ',6,6' -tetramethoxybiphenyl" --- p.53 / Chapter 2.7 --- Synthesis of other tetraphenylene derivatives --- p.57 / Chapter 2.8 --- X-ray crystallographic studies of tetraphenylene derivatives --- p.59 / Chapter 2.8.1 --- "X-ray crystallographic studies of 1,4,5,8,9,12,13,16-octamethoxytetraphenylene" --- p.59 / Chapter 2.8.2 --- "X-Ray crystallographic studies of 1,4,5,8,9,12,13,16-octahydroxytetraphenylene" --- p.61 / Chapter 2.9 --- "Electrochemical properties of 1,4,5,8,9,12,13,16-octamethoxytetraphenylene and l,4,5,8,9,12,13,16-octahydro-l,4,5,8,9,12,13,16-octaoxo- tetraphenylene" --- p.62 / Chapter 2.9.1 --- "Electrochemical properties of 1,4,5,8,9,12,13,16-octamethoxytetraphenylene" --- p.65 / Chapter 2.9.2 --- "Electrochemical properties of 1,4,5,8,9,12,13,16-octahydro-1,4,5,8,9,12,13,16-octaoxo- tetraphenylene" --- p.66 / Chapter CHAPTER 3 --- CONCLUSION --- p.69 / Chapter CHAPTER 4 --- EXPERIMENTAL SECTION --- p.70 / REFERENCES --- p.87 / APPENDICES --- p.93 / Chapter I. --- List of NMR spectra --- p.95 / Chapter II. --- List of cyclic voltammetric data --- p.109 / Chapter III. --- List of X-ray crystallographic data --- p.111
| Identifer | oai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_324225 |
| Date | January 2003 |
| Contributors | Lai, Chun Wing., Chinese University of Hong Kong Graduate School. Division of Chemistry. |
| Source Sets | The Chinese University of Hong Kong |
| Language | English, Chinese |
| Detected Language | English |
| Type | Text, bibliography |
| Format | print, 123 leaves : ill. ; 30 cm. |
| Rights | Use of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/) |
Page generated in 0.0015 seconds