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Luminescent sp²-Carbon-Linked 2D Conjugated Polymers with High Photostability

Luminescent organic materials with high photostability are essential in optoelectronics, sensor, and photocatalysis applications. However, small organic molecules are generally sensitive to UV irradiation, giving rise to chemical decompositions. In this work, we demonstrate two novel CN-substituted two-dimensional sp²-carbon-linked conjugated polymers (2D CCPs) containing a chromophore triphenylene unit. The Knoevenagel polymerization between 2,3,6,7,10,11-hexakis(4-formylphenyl)triphenylene (HFPTP) and 1,4-phenylenediacetonitrile (PDAN) or 2,2’-(biphenyl-4,4’-diyl)diacetonitrile (BDAN), provides the crystalline 2D CCP-HFPTP-PDAN (2D CCP-1) and 2D CCP-HFPTP-BDAN (2D CCP-2) with dual pore structures, respectively. 2D CCP-1 and 2D CCP-2 exhibit the photoluminescence quantum yield (PLQY) up to 24.9% and 32.3%, which are the highest values among the reported 2D conjugated polymers and π-conjugated 2D covalent organic frameworks. Furthermore, compared with the well-known emissive small molecule tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN), both 2D CCPs show superior photostability under UV irradiation for two hours, profiting from the twisted and rigid structures of the CN-substituted vinylene linkages. The present work will trigger the further explorations of novel organic emitters embedded in 2D CCPs with high PLQY and photostability, which can be useful for optoelectronic devices.

Identiferoai:union.ndltd.org:DRESDEN/oai:qucosa:de:qucosa:73362
Date28 September 2021
CreatorsXu, Shunqi, Li, Yungui, Biswal, Bishnu P., Addicoat, Matthew A., Paasch, Silvia, Imbrasas, Paulius, Park, SangWook, Shi, Huanhuan, Brunner, Eike, Richter, Marcus, Lenk, Simone, Reineke, Sebastian, Feng, Xinliang
PublisherAmerican Chemical Society
Source SetsHochschulschriftenserver (HSSS) der SLUB Dresden
LanguageEnglish
Detected LanguageEnglish
Typeinfo:eu-repo/semantics/acceptedVersion, doc-type:article, info:eu-repo/semantics/article, doc-type:Text
Rightsinfo:eu-repo/semantics/openAccess
Relation10.1021/acs.chemmater.0c02910, info:eu-repo/grantAgreement/Europäische Union/H2020-MSCA-ITN/881603//Graphene Flagship (GrapheneCore3), info:eu-repo/grantAgreement/European Commission/H2020/819698//Development of Thiophene Based Conjugated Polymers in Two Dimensions/T2DCP, info:eu-repo/grantAgreement/Deutsche Forschungsgemeinschaft/Koordinationsnetzwerke als Bausteine für Funktionssysteme/434440165//Building Blocks for Functional Systems/COORNET

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